{"id":"W1979922351","doi":"10.1002/ange.201411134","title":"Titelbild: Frustrated Lewis Pair Activation of an <i>N</i>‐Sulfinylamine: A Source of Sulfur Monoxide (Angew. Chem. 3/2015)","year":2014,"lang":"de","type":"article","venue":"Angewandte Chemie","topic":"Chemical Synthesis and Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Lewis acids and bases; Medicinal chemistry; Polymer chemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0004226962,0.0006009972,0.001012351,0.0001193886,0.0001202362,0.0000487378,0.0005665114,0.0008892614,0.001096617],"category_scores_gemma":[0.0006527038,0.0005821967,0.0004545836,0.0005436913,0.0003648398,0.0002874984,0.0001433433,0.0005938644,0.00005312811],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001874061,"about_ca_system_score_gemma":0.0001493629,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001167561,"about_ca_topic_score_gemma":0.00002510565,"domain_scores_codex":[0.9967904,0.0000641122,0.001126805,0.0007880343,0.0006078432,0.0006227758],"domain_scores_gemma":[0.9964621,0.00054109,0.001020088,0.001211709,0.0003918683,0.0003731163],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000162567,0.001076857,0.001162504,0.0007708166,0.0003540211,0.000002016107,0.0004101987,0.00002053958,0.9861468,0.00002342213,0.005350757,0.00451947],"study_design_scores_gemma":[0.001117481,0.00009894966,0.0003529682,0.0004867307,0.0003995469,0.000006194176,0.0003683144,0.0001704997,0.9239891,0.0001248057,0.07232545,0.0005599126],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9881626,0.0009226606,0.0001566674,0.0005539164,0.0001589262,0.0001991376,0.0001629071,0.0001334507,0.009549721],"genre_scores_gemma":[0.994523,0.0002776262,0.0004505645,0.00008677383,0.001099269,0.00003222888,0.0005683538,0.0001161527,0.002845971],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.06697469,"threshold_uncertainty_score":0.9998165,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0131296881782195,"score_gpt":0.2376528765422241,"score_spread":0.2245231883640046,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}