{"id":"W1979934782","doi":"10.1002/chem.201202601","title":"Synthesis of Imides by Palladium‐Catalyzed CH Functionalization of Aldehydes with Secondary Amides","year":2012,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":24,"is_retracted":false,"has_abstract":true,"ca_institutions":"Ministry of Education and Child Care","funders":"National Natural Science Foundation of China","keywords":"Surface modification; Palladium; Catalysis; Chemistry; Combinatorial chemistry; Catalytic cycle; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.001078784,0.0002811803,0.0003820794,0.00006131506,0.0001397834,0.00003864684,0.0003006599,0.00007475352,0.01014159],"category_scores_gemma":[0.0007364103,0.0002510324,0.0001724472,0.0002520009,0.0002799017,0.000305184,0.00007637507,0.0003270438,0.00001403019],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00010673,"about_ca_system_score_gemma":0.0001672059,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000003829827,"about_ca_topic_score_gemma":2.068341e-7,"domain_scores_codex":[0.9979334,0.0001207962,0.0008245678,0.000246531,0.00055337,0.0003213227],"domain_scores_gemma":[0.9976528,0.0003273385,0.0009398615,0.0003946592,0.0004132648,0.0002720866],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002225717,0.0002467818,0.008465364,0.0006761248,0.0003040833,0.000007789178,0.0001966117,0.0001295557,0.9811062,0.00004437594,0.00475359,0.003846984],"study_design_scores_gemma":[0.0008966599,0.00001476307,0.002043907,0.0003058609,0.0002085682,0.0006918557,0.0004662761,0.0001249862,0.9780415,0.00002666045,0.01687901,0.0002999308],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9427543,0.001572942,0.0139165,0.00008413768,0.0001377988,0.00005137467,0.0001959616,0.00006841811,0.04121862],"genre_scores_gemma":[0.9922929,0.0001218226,0.004008722,0.00003178718,0.0006160268,0.000005655893,0.0002663212,0.00009224826,0.002564455],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04953872,"threshold_uncertainty_score":0.9999942,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01622976383231855,"score_gpt":0.2341871279682489,"score_spread":0.2179573641359303,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}