{"id":"W1979985714","doi":"10.1002/pca.943","title":"Analysis of bisdesmosidic saponins in <i>Saponaria vaccaria</i> L. by HPLC‐PAD‐MS: identification of new quillaic acid and gypsogenin 3‐O‐Trisaccharides","year":2006,"lang":"en","type":"article","venue":"Phytochemical Analysis","topic":"Natural product bioactivities and synthesis","field":"Biochemistry, Genetics and Molecular Biology","cited_by":24,"is_retracted":false,"has_abstract":true,"ca_institutions":"Plant Biotechnology Institute","funders":"Ministry of Agriculture - Saskatchewan","keywords":"Chemistry; Electrospray; Chromatography; Pentose; Mass spectrometry; Mass spectrum; Electrospray mass spectrometry; Electrospray ionization; High-performance liquid chromatography; Stereochemistry; Biochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00005168611,0.0003720919,0.0001523304,0.0003634338,0.000109951,0.0002004469,0.0000959515,0.0001779295,0.0004557204],"category_scores_gemma":[0.0001067899,0.00009097748,0.0001437717,0.0001859825,0.0001426689,0.0001983785,0.0001256141,0.0002227281,0.0001549802],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001650277,"about_ca_system_score_gemma":0.0001322557,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005934655,"about_ca_topic_score_gemma":0.001016215,"domain_scores_codex":[0.9999706,0.000004791223,0.000002573126,0.000009396535,0.000007740768,0.000004874523],"domain_scores_gemma":[0.9999222,0.00001994206,0.00001925731,0.000005513335,0.00001511839,0.00001787772],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001604344,0.000003596488,0.0002634343,0.00001116798,0.000001466852,0.0000204296,0.0000070448,0.000008345778,0.9990901,0.000008904382,0.000002724251,0.0005667629],"study_design_scores_gemma":[0.00001054997,0.0002561143,0.04794094,0.000008648939,0.00002980586,0.0004158359,0.00004892403,0.0007245052,0.9492342,0.00006671884,0.001255778,0.000008067619],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9951839,0.00051615,0.003150055,0.0000304657,0.000004330684,0.00002275689,0.0003302903,0.0000529583,0.0007089088],"genre_scores_gemma":[0.9915072,0.0006845092,0.005296958,0.00007914902,0.000007422705,0.00003138507,0.001084425,0.00002071813,0.001288213],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0005934655,"threshold_uncertainty_score":0.001524508,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004828079624414706,"score_gpt":0.2254979581224526,"score_spread":0.2206698784980379,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}