{"id":"W1980206640","doi":"10.1039/b104884h","title":"The relaxation of electronically excited molecules: Effects of alkyl substitution on the S2 and T1 states of benzopyranthione in solution","year":2001,"lang":"en","type":"article","venue":"Physical Chemistry Chemical Physics","topic":"Photochemistry and Electron Transfer Studies","field":"Chemistry","cited_by":19,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Saskatchewan","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Excited state; Intramolecular force; Alkyl; Photochemistry; Relaxation (psychology); Phosphorescence; Absorption spectroscopy; Quenching (fluorescence); Solvent; Triplet state; Solvent effects; Molecule; Fluorescence; Emission spectrum; Ground state; Spectral line; Stereochemistry; Atomic physics; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001094539,0.0002468459,0.0003983757,0.000006987331,0.00008104868,0.00000800045,0.0002722718,0.0001194794,0.000004570872],"category_scores_gemma":[0.0002473248,0.0001743833,0.0001515868,0.0002859237,0.0006502798,0.00005558873,0.00005513149,0.0004618427,5.509604e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008160348,"about_ca_system_score_gemma":0.00005221238,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002533139,"about_ca_topic_score_gemma":0.00000121083,"domain_scores_codex":[0.9985532,0.00002418057,0.0004253109,0.0003010542,0.000356938,0.0003392708],"domain_scores_gemma":[0.9982183,0.0009979915,0.0002456115,0.0003566213,0.0001298645,0.00005158749],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003864655,0.0005861765,0.00009999592,0.0007073688,0.00008678145,9.473573e-7,0.0002444346,0.00007538102,0.9955336,0.001551319,0.00001645285,0.0007110993],"study_design_scores_gemma":[0.0006791652,0.00004255645,0.00009145437,0.0002385776,0.00006166816,0.000001305719,0.00005091375,0.003092659,0.9865541,0.009003864,0.00002708791,0.0001566107],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9977999,0.0003462848,0.0003110414,0.0002174287,0.000006284281,0.0001223425,0.00001490764,0.00002039279,0.001161436],"genre_scores_gemma":[0.9992821,0.0004656689,0.000009271165,0.00001133321,0.00008883129,0.00005396141,0.00004968177,0.0000160831,0.00002306302],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00897944,"threshold_uncertainty_score":0.7111145,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006207275038752049,"score_gpt":0.2188417614882623,"score_spread":0.2126344864495102,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}