{"id":"W1980323244","doi":"10.1021/jp010849h","title":"Effect of Pressure on the Vibronic Luminescence Spectrum of a <i>trans</i>-Dioxo Rhenium(V) Complex","year":2001,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry A","topic":"Magnetism in coordination complexes","field":"Materials Science","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal; McGill University","funders":"","keywords":"Rhenium; Tetramethylethylenediamine; Luminescence; Chemistry; Ground state; Vibronic spectroscopy; High pressure; Spectral line; Atomic physics; Materials science; Physics; Inorganic chemistry; Polymer chemistry; Optoelectronics; Thermodynamics; Organic chemistry; Molecule","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0009300903,0.0001591979,0.0003872799,0.00001492358,0.00007208648,0.00001675592,0.0009451818,0.000034804,0.001078683],"category_scores_gemma":[0.0001902594,0.00008164894,0.0001832423,0.0001927031,0.0003746694,0.00007719778,0.00006940438,0.0002612697,0.000006090323],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001697745,"about_ca_system_score_gemma":0.00004172463,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001248024,"about_ca_topic_score_gemma":5.96991e-7,"domain_scores_codex":[0.9984406,0.000272493,0.0003953476,0.0001091832,0.0005881831,0.0001941637],"domain_scores_gemma":[0.9974674,0.0013951,0.000571039,0.0003929902,0.000119484,0.00005399585],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004737953,0.0001424448,0.00002048194,0.0001968373,0.00002180324,0.00000229785,0.0001889886,0.001640546,0.9963471,0.0001738249,0.0006540205,0.000137814],"study_design_scores_gemma":[0.0004372936,0.0006371731,0.0003522578,0.0001256434,0.0001053973,0.00006371107,0.00002067963,0.001939928,0.9946349,0.0005431633,0.001062217,0.00007769617],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9951071,0.000112098,0.0004826843,0.001453339,0.00003978223,0.0001348771,0.00001678381,0.000009266935,0.002644096],"genre_scores_gemma":[0.9994307,0.00001345775,0.00002165297,0.00003411238,0.0003090444,0.000002409667,5.424193e-7,0.0000103475,0.0001777067],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004323653,"threshold_uncertainty_score":0.9998345,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0115812924421284,"score_gpt":0.2559874874984266,"score_spread":0.2444061950562982,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}