{"id":"W1980682265","doi":"10.1002/jbm.a.30739","title":"<i>In vitro</i> homogeneous and heterogeneous degradation of poly(ϵ‐caprolactone/polyethylene glycol/<scp>L</scp>‐lactide): The absence of autocatalysis and the role of enzymes","year":2006,"lang":"en","type":"article","venue":"Journal of Biomedical Materials Research Part A","topic":"biodegradable polymer synthesis and properties","field":"Materials Science","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval; Hôpital Saint-François d'Assise","funders":"","keywords":"Autocatalysis; Materials science; Differential scanning calorimetry; Polyethylene glycol; Polymer; Caprolactone; Gel permeation chromatography; Membrane; PEG ratio; Biodegradable polymer; Polymer chemistry; Hydrolysis; Aqueous solution; Lactide; Chemical engineering; Nuclear chemistry; Copolymer; Organic chemistry; Chemistry; Biochemistry; Composite material","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003463173,0.0004675577,0.000225469,0.0001468652,0.00009618722,0.0003055525,0.0001588472,0.00030815,0.0003613547],"category_scores_gemma":[0.0003365753,0.0001342467,0.0002565748,0.0001459043,0.0002184865,0.0003706773,0.0001383469,0.0003091567,0.0002180881],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002468042,"about_ca_system_score_gemma":0.0001367064,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004427358,"about_ca_topic_score_gemma":0.0003700095,"domain_scores_codex":[0.9997286,0.0000653316,0.00002476149,0.00005586984,0.00006229991,0.00006300712],"domain_scores_gemma":[0.9996684,0.00009255105,0.0001316137,0.00002999431,0.00004748869,0.000030135],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006284335,0.00001177544,0.00006625539,0.0000263774,0.000004696766,0.00001891359,0.00000859708,0.00006780027,0.999151,0.00001024939,0.00000584397,0.0005655839],"study_design_scores_gemma":[0.000002004501,0.0001582695,0.0006078709,0.00000142182,0.000007134988,0.00003768661,0.000004234842,0.0002221554,0.9987773,0.000005214933,0.0001748477,0.000001711036],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9940957,0.001541157,0.003554875,0.00002054623,0.00001201507,0.00001839428,0.00009620706,0.00003871327,0.0006225553],"genre_scores_gemma":[0.9952473,0.0007516271,0.002793287,0.0000295367,0.000008705251,0.00002412015,0.0002384643,0.00002240856,0.0008845712],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0004675577,"threshold_uncertainty_score":0.001831532,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01827086575070861,"score_gpt":0.2670304389069864,"score_spread":0.2487595731562778,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}