{"id":"W1980713588","doi":"10.1021/ja046308y","title":"Organogermanium Reactive Intermediates. The Direct Detection and Characterization of Transient Germylenes and Digermenes in Solution","year":2004,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":73,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Chemistry; Flash photolysis; Reaction rate constant; Quantum yield; Isoprene; Methanol; Lambda; Yield (engineering); Ultrafast laser spectroscopy; Photodissociation; Analytical Chemistry (journal); Photochemistry; Kinetics; Laser; Fluorescence; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001581243,0.0001150415,0.0002713153,0.00002034417,0.00006378291,0.00002426437,0.0001543074,0.00004887262,0.00001491988],"category_scores_gemma":[0.00004929614,0.00007104121,0.0001328656,0.0002184814,0.0003531227,0.0001267154,0.00006068305,0.0001951319,1.142905e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000136081,"about_ca_system_score_gemma":0.00004179555,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003002537,"about_ca_topic_score_gemma":0.000003076384,"domain_scores_codex":[0.9991823,0.00002493186,0.0003711766,0.0001183738,0.000187542,0.0001156138],"domain_scores_gemma":[0.9989906,0.00009229455,0.000684572,0.0001142228,0.00007910814,0.00003923108],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004720472,0.00007681466,0.002580808,0.0000237808,0.00005388926,3.085389e-7,0.001600185,7.847922e-7,0.991601,0.000001882059,0.00000150296,0.004011815],"study_design_scores_gemma":[0.0003039856,0.00002276817,0.1065238,0.00006829098,0.00004491967,0.00004432201,0.0004465119,0.00004123403,0.8922095,0.00003032426,0.0001903217,0.00007400474],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9983391,0.00005029173,0.0001087204,0.00136399,0.00005673208,0.00003910555,0.00000716399,0.000006264785,0.00002864802],"genre_scores_gemma":[0.9991791,0.0005188545,0.00003689675,0.0001183279,0.0001187359,0.000002246129,0.000001801397,0.00001283464,0.00001115513],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.103943,"threshold_uncertainty_score":0.2896976,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006525785594850161,"score_gpt":0.2049792163958206,"score_spread":0.1984534308009704,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}