{"id":"W1980713588","doi":"10.1021/ja046308y","title":"Organogermanium Reactive Intermediates. The Direct Detection and Characterization of Transient Germylenes and Digermenes in Solution","year":2004,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":73,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Chemistry; Flash photolysis; Reaction rate constant; Quantum yield; Isoprene; Methanol; Lambda; Yield (engineering); Ultrafast laser spectroscopy; Photodissociation; Analytical Chemistry (journal); Photochemistry; Kinetics; Laser; Fluorescence; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001588769,0.0004960759,0.0002034828,0.0001716794,0.0001198146,0.0003248893,0.0003612483,0.0004206705,0.001536389],"category_scores_gemma":[0.0002391183,0.0001498054,0.000138039,0.0001386854,0.0002323873,0.0003426771,0.0002576261,0.0003833424,0.0004504562],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002960039,"about_ca_system_score_gemma":0.0001169693,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001793736,"about_ca_topic_score_gemma":0.0002611682,"domain_scores_codex":[0.9998834,0.00001769921,0.000004895547,0.00004381455,0.00002994993,0.00002026974],"domain_scores_gemma":[0.9998884,0.0000348848,0.00003485301,0.000009321436,0.00001671613,0.00001591259],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003338429,0.000004271837,0.0001103256,0.0000465801,0.000003725258,0.00003093989,0.00001829406,0.00002714207,0.9984901,0.00007952726,0.00001543485,0.001140354],"study_design_scores_gemma":[0.000003652326,0.0001240277,0.0006757648,0.000002652255,0.000007085927,0.0001598515,0.00001936266,0.0001805529,0.9975988,0.00003879216,0.001186426,0.000002820671],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9795625,0.003391069,0.01337266,0.00006108766,0.00002515024,0.00005380931,0.0004345323,0.0001759033,0.002923259],"genre_scores_gemma":[0.9878879,0.001342917,0.007216969,0.00004557801,0.000008550903,0.00004997308,0.0004620655,0.0000257999,0.002960197],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001536389,"threshold_uncertainty_score":0.005139768,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006525785594850161,"score_gpt":0.2049792163958206,"score_spread":0.1984534308009704,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}