{"id":"W1980727769","doi":"10.1016/s0891-5849(00)00298-7","title":"How should xanthine oxidase–generated superoxide yields be measured?","year":2000,"lang":"en","type":"article","venue":"Free Radical Biology and Medicine","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":31,"is_retracted":false,"has_abstract":true,"ca_institutions":"Steacie Institute for Molecular Sciences","funders":"National Foundation for Cancer Research","keywords":"Superoxide; Chemistry; Xanthine oxidase; Hydrogen peroxide; Electron transfer; Tetranitromethane; Superoxide dismutase; Photochemistry; Oxygen; Cytochrome c oxidase; Enzyme; Biochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0005153549,0.0002829669,0.0005094148,0.00008144096,0.0001663117,0.00001315932,0.000348571,0.0006311391,0.01794595],"category_scores_gemma":[0.001132517,0.0001987376,0.00006118036,0.0001804297,0.0007459137,0.00006952696,0.0000524624,0.0005132384,0.00002111159],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002786633,"about_ca_system_score_gemma":0.00004438226,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000914225,"about_ca_topic_score_gemma":0.00005345588,"domain_scores_codex":[0.9983714,0.00008891994,0.0003517044,0.0005089155,0.000271619,0.0004074267],"domain_scores_gemma":[0.9987468,0.0001901115,0.00006584662,0.0005430178,0.00006548945,0.0003887821],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000997911,0.00006554741,0.0002472118,0.00004187971,0.0001131201,0.0000472688,0.0001053565,6.088169e-7,0.9566988,0.005726939,0.01720711,0.01964641],"study_design_scores_gemma":[0.004712943,0.0002874641,0.0001920394,0.00009341601,0.0001835368,0.0002392454,0.0001189414,0.0003745856,0.5603964,0.006270114,0.4266826,0.0004487098],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8994507,0.006785267,0.001667043,0.079269,0.0004499231,0.0001798934,0.0001899748,0.0003204801,0.01168776],"genre_scores_gemma":[0.9797526,0.001144547,0.001005371,0.004305291,0.001128772,0.00003184779,0.0008558178,0.00003333906,0.0117424],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.4094754,"threshold_uncertainty_score":0.9829518,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04456786840877777,"score_gpt":0.2797109779205023,"score_spread":0.2351431095117245,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}