{"id":"W1981111438","doi":"10.1021/ol902000j","title":"An Unprecedented Oxidative Wagner−Meerwein Transposition","year":2009,"lang":"en","type":"article","venue":"Organic Letters","topic":"Oxidative Organic Chemistry Reactions","field":"Chemistry","cited_by":74,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université du Québec à Montréal","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Hypervalent molecule; Umpolung; Chemistry; Transposition (logic); Oxidative phosphorylation; Reagent; Iodine; Combinatorial chemistry; Ring (chemistry); Nucleophile; Organic chemistry; Catalysis; Biochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00006795532,0.0002866652,0.0002154148,0.00004886562,0.0001633627,0.00006657825,0.0003573939,0.0001472848,0.007221666],"category_scores_gemma":[0.00002540697,0.0003082104,0.00009068672,0.0002957927,0.00007183226,0.0002798988,0.00001098305,0.0003563005,0.0002111804],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003397695,"about_ca_system_score_gemma":0.00004270424,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001406804,"about_ca_topic_score_gemma":0.000009896504,"domain_scores_codex":[0.9985344,0.00002891755,0.0002756628,0.0005044694,0.0002790984,0.000377421],"domain_scores_gemma":[0.9990231,0.00004094939,0.0001122034,0.0005786721,0.00005297008,0.0001921539],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002683617,0.0002113474,0.0002132331,0.00001361175,0.00004019521,0.00002076747,0.0004839562,0.000006623604,0.9967476,0.00004191844,0.001249126,0.0009448178],"study_design_scores_gemma":[0.0006756618,0.0000381199,0.00160601,0.00003165748,0.00006590808,0.00004728937,0.000277489,0.00006862747,0.9960083,0.00005399499,0.0007746778,0.000352301],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9857388,0.00001795898,0.001299874,0.00899053,0.00005803066,0.00006856945,0.00003889084,0.0004299599,0.003357403],"genre_scores_gemma":[0.9962595,0.0000082825,0.0004170137,0.002343815,0.0003180594,0.000006640652,0.000313192,0.00004757191,0.0002859262],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01052072,"threshold_uncertainty_score":0.999937,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006867823196816903,"score_gpt":0.2294043661367184,"score_spread":0.2225365429399015,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}