{"id":"W1981111438","doi":"10.1021/ol902000j","title":"An Unprecedented Oxidative Wagner−Meerwein Transposition","year":2009,"lang":"en","type":"article","venue":"Organic Letters","topic":"Oxidative Organic Chemistry Reactions","field":"Chemistry","cited_by":74,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université du Québec à Montréal","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Hypervalent molecule; Umpolung; Chemistry; Transposition (logic); Oxidative phosphorylation; Reagent; Iodine; Combinatorial chemistry; Ring (chemistry); Nucleophile; Organic chemistry; Catalysis; Biochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000326438,0.0008422165,0.0003757325,0.0003298299,0.000286445,0.0007190518,0.0009178708,0.0006304125,0.001521881],"category_scores_gemma":[0.0002779872,0.0002947277,0.0004253052,0.0004108108,0.0005244016,0.0006167843,0.001436506,0.0009572619,0.0007074711],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003861113,"about_ca_system_score_gemma":0.0003549581,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003652852,"about_ca_topic_score_gemma":0.000490816,"domain_scores_codex":[0.9996884,0.00003160694,0.0000240563,0.00007612411,0.0000598322,0.0001200368],"domain_scores_gemma":[0.9999154,0.00001253462,0.00002290686,0.00002079316,0.000008063156,0.00002027785],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001321293,0.000097417,0.0003517042,0.0002378844,0.00005751156,0.0007070337,0.0002250849,0.001205559,0.9558776,0.0161036,0.0008081134,0.02419627],"study_design_scores_gemma":[0.00003343667,0.00041271,0.0004483305,0.00001027912,0.00003650002,0.0005109437,0.00003408077,0.001561321,0.9812806,0.0007862089,0.01484052,0.00004506261],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9292297,0.00282196,0.04400912,0.0004965942,0.0004412085,0.000231652,0.0005024814,0.001009085,0.02125821],"genre_scores_gemma":[0.9761544,0.001666246,0.01234031,0.0001596839,0.00003542639,0.00007785727,0.0003473923,0.00006977517,0.009149007],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001521881,"threshold_uncertainty_score":0.00509119,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006867823196816903,"score_gpt":0.2294043661367184,"score_spread":0.2225365429399015,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}