{"id":"W1981165361","doi":"10.1007/s10953-011-9715-1","title":"Experimental Determination of a Third Derivative of G. (III): Differential Pressure Perturbation Calorimetry (II)","year":2011,"lang":"en","type":"article","venue":"Journal of Solution Chemistry","topic":"Thermodynamic properties of mixtures","field":"Chemical Engineering","cited_by":15,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of British Columbia","funders":"","keywords":"Chemistry; Aqueous solution; Thermodynamics; Derivative (finance); Gibbs free energy; Second derivative; Differential scanning calorimetry; Calorimetry; Enthalpy; Heat capacity; Perturbation (astronomy); Entropy (arrow of time); Physical chemistry; Mathematical analysis; Physics; Mathematics; Quantum mechanics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0006089938,0.0005808588,0.000285226,0.0003110096,0.0005373384,0.0003857823,0.0007047608,0.0008429158,0.002635587],"category_scores_gemma":[0.001037998,0.0003107169,0.0002480855,0.0004557408,0.001129487,0.0004069455,0.000360731,0.001787882,0.0008524997],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004471212,"about_ca_system_score_gemma":0.000487697,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001333348,"about_ca_topic_score_gemma":0.001139975,"domain_scores_codex":[0.9994642,0.00008910228,0.00002436952,0.0001504072,0.0001624492,0.000109465],"domain_scores_gemma":[0.9996095,0.0001279962,0.00004642749,0.00009283688,0.00009381983,0.00002937073],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005777102,0.00002164515,0.00022525,0.00003590667,0.000005328222,0.00001797491,0.00003586793,0.000111503,0.9973099,0.0003840585,0.0002369095,0.001557869],"study_design_scores_gemma":[0.000003144758,0.00002124233,0.0005843947,0.000002274789,0.000003004827,0.00003241291,0.0000109021,0.0004721903,0.99829,0.00005902843,0.0005172103,0.000004265249],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.895402,0.001221769,0.09050193,0.0007392471,0.000321163,0.0001087456,0.001701017,0.001213371,0.008790698],"genre_scores_gemma":[0.9776444,0.0004443528,0.01927008,0.0002330816,0.00002033818,0.00009411726,0.0006767847,0.0001428317,0.001473969],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002635587,"threshold_uncertainty_score":0.008816957,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01597221389106609,"score_gpt":0.225532402710811,"score_spread":0.2095601888197449,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}