{"id":"W1981303914","doi":"10.1002/cjoc.200990174","title":"Electrocatalytic Carboxylation of Benzyl Chloride at Silver Cathode in Ionic Liquid BMIMBF<sub>4</sub>","year":2009,"lang":"en","type":"article","venue":"Chinese Journal of Chemistry","topic":"Ionic liquids properties and applications","field":"Chemical Engineering","cited_by":37,"is_retracted":false,"has_abstract":true,"ca_institutions":"Tellabs (Canada)","funders":"","keywords":"Chemistry; Ionic liquid; Tetrafluoroborate; Cyclic voltammetry; Carboxylation; Phenylacetic acid; Inorganic chemistry; Yield (engineering); Chloride; Electrochemistry; Cathode; Benzyl chloride; Ionic bonding; Electrode; Organic chemistry; Ion; Catalysis; Physical chemistry; Metallurgy","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001583995,0.0003965788,0.0003453225,0.0001556498,0.0001341941,0.0002246958,0.0004115165,0.0004259768,0.0007851948],"category_scores_gemma":[0.0003299479,0.0001731044,0.0002044455,0.0001610679,0.0001874673,0.0002819074,0.0002764999,0.0003300432,0.0003959455],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000237257,"about_ca_system_score_gemma":0.0001741462,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008214994,"about_ca_topic_score_gemma":0.001055946,"domain_scores_codex":[0.9998381,0.0000206856,0.00001098402,0.00003032392,0.00005860191,0.00004124158],"domain_scores_gemma":[0.9998651,0.0000226968,0.00004216895,0.00001024382,0.00004347489,0.00001626011],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003492401,0.000002374244,0.00003299737,0.00002869477,0.000001283336,0.00002474054,0.000006899003,0.00001426229,0.9993468,0.00001546627,0.00001362217,0.0004779156],"study_design_scores_gemma":[0.000003673039,0.00003186589,0.0002003486,0.000001872762,0.000002884924,0.0000323637,0.000004088406,0.0002278605,0.9992707,0.000006010061,0.0002168677,0.00000136729],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9907449,0.001255415,0.005874771,0.0001743813,0.00004261099,0.00002286111,0.0001166245,0.0001476529,0.001620668],"genre_scores_gemma":[0.9941338,0.000564163,0.003429468,0.00004315065,0.000008270856,0.00001408935,0.00009973547,0.00003188826,0.00167536],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008214994,"threshold_uncertainty_score":0.002626777,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005310185423912778,"score_gpt":0.2182370843139573,"score_spread":0.2129268988900445,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}