{"id":"W1981632620","doi":"10.1021/om000085c","title":"Agostic Bonding in Pincer Complexes of Ruthenium","year":2000,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":109,"is_retracted":false,"has_abstract":true,"ca_institutions":"Wilfrid Laurier University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Agostic interaction; Chemistry; Ruthenium; Crystallography; Antibonding molecular orbital; Hydride; Pincer movement; Iodide; Stereochemistry; Inorganic chemistry; Hydrogen; Metal; Electron; Organic chemistry; Atomic orbital; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001693778,0.0002434305,0.0005426253,0.0001919351,0.00005939647,0.00003449105,0.0004530115,0.0001047956,0.2879636],"category_scores_gemma":[0.00006706222,0.0002392331,0.0001900264,0.0007484265,0.0001252079,0.0001254518,0.00007958502,0.0001631645,0.0002915619],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008062837,"about_ca_system_score_gemma":0.00004337277,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006839354,"about_ca_topic_score_gemma":0.00008358874,"domain_scores_codex":[0.9983438,0.00002226818,0.0005882967,0.0003715486,0.0003038174,0.0003703209],"domain_scores_gemma":[0.9990077,0.0001422002,0.0001318129,0.0005868032,0.00003360008,0.00009786312],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"not_applicable","study_design_scores_codex":[0.0000580156,0.0006480017,0.006821428,0.0002834241,0.0002165149,0.00001875408,0.0009837437,0.00005094075,0.8901264,0.009313659,0.00007264813,0.09140644],"study_design_scores_gemma":[0.002273371,0.00007653423,0.04096843,0.0003054334,0.0004847942,0.00005265791,0.001401054,0.0007067079,0.4685021,0.005327576,0.4780816,0.001819745],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9021211,0.0004925206,0.00001460619,0.0001090214,0.00002531303,0.00004783902,0.00006187884,0.00005466176,0.09707312],"genre_scores_gemma":[0.9745452,0.0001312105,0.0003569123,0.00003520888,0.00007505276,0.00001037038,0.00004907065,0.00004884555,0.02474809],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.478009,"threshold_uncertainty_score":0.9755644,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01231945981270956,"score_gpt":0.2218334370639931,"score_spread":0.2095139772512835,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}