{"id":"W1981957804","doi":"10.1021/ac030005p","title":"Kinetics of Metal−Fulvic Acid Complexation Using a Stopped-Flow Technique and Three-Dimensional Excitation Emission Fluorescence Spectrophotometer","year":2003,"lang":"en","type":"article","venue":"Analytical Chemistry","topic":"Marine and coastal ecosystems","field":"Earth and Planetary Sciences","cited_by":65,"is_retracted":false,"has_abstract":true,"ca_institutions":"Trent University","funders":"","keywords":"Chemistry; Fluorescence; Kinetics; Metal; Analytical Chemistry (journal); Kinetic energy; Fluorescence spectrometry; Fluorescence spectroscopy; Chromatography; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001368747,0.000116434,0.0001844449,0.00003643851,0.00004308418,0.00002018934,0.00006852081,0.00008015477,0.00132632],"category_scores_gemma":[0.00009724662,0.00009852069,0.00004855978,0.0002039377,0.00007649541,0.0000748559,0.00001412116,0.000107393,0.000004256583],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000007169901,"about_ca_system_score_gemma":0.00002366986,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002203429,"about_ca_topic_score_gemma":0.00006149444,"domain_scores_codex":[0.9991006,0.00002832492,0.000249394,0.0002152743,0.0002430491,0.0001633234],"domain_scores_gemma":[0.9995416,0.00005856355,0.00009402228,0.0001352142,0.00006322691,0.0001073753],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004899556,0.0000543117,0.04509649,0.0002261802,0.00003279651,0.00001473715,0.00001389835,0.0004832371,0.9518591,0.00005934839,0.00004794287,0.002063018],"study_design_scores_gemma":[0.0003012068,0.0001164007,0.01481881,0.00008022501,0.00007207086,0.0001254998,0.00002886544,0.4483393,0.5336295,0.001995558,0.00023584,0.0002566669],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.990516,0.0001126374,0.004263125,0.00002119633,0.00002331669,0.000114767,0.00002146914,0.00001544888,0.004912056],"genre_scores_gemma":[0.9930899,0.000004996689,0.006714717,0.00001577648,0.00002086849,8.024739e-7,0.0000548292,0.000003235695,0.00009492702],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.4478561,"threshold_uncertainty_score":0.9995866,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01903566644476032,"score_gpt":0.2280537095248485,"score_spread":0.2090180430800882,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}