{"id":"W1982041156","doi":"10.1139/v01-204","title":"The first observed complex of 11-crown-3 ether. X-ray crystal structure and NMR study of (benzo-11-crown-3)<sub>2</sub>·LiNCS","year":2002,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Molecular Sensors and Ion Detection","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Crown ether; Crystallography; Crystal structure; NMR spectra database; Monoclinic crystal system; Relaxation (psychology); Dimer; Solid-state nuclear magnetic resonance; Stereochemistry; Spectral line; Nuclear magnetic resonance; Ion; Organic chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001714358,0.0002593655,0.0004349652,0.00005483452,0.0002789064,0.0000722059,0.0004173913,0.0002340851,0.0007217192],"category_scores_gemma":[0.000191272,0.0002155156,0.0001785099,0.0001774838,0.0002483844,0.00007436841,0.00003296916,0.0004630162,5.823794e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001101237,"about_ca_system_score_gemma":0.00016604,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001029521,"about_ca_topic_score_gemma":0.01456136,"domain_scores_codex":[0.998248,0.00003417122,0.0007751649,0.0002218246,0.0003756335,0.0003451595],"domain_scores_gemma":[0.9978969,0.0000906247,0.0007498401,0.000445455,0.0003496565,0.0004675628],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004801203,0.00006696535,0.006352207,0.0002302616,0.0001363358,0.0001161318,0.0009087662,0.0002590285,0.9885116,0.000002054112,0.002385135,0.0009835274],"study_design_scores_gemma":[0.001852291,0.0001151338,0.008045138,0.0001787976,0.0001242302,0.0004639726,0.003186026,0.0004452211,0.9728368,0.00004070107,0.01238975,0.0003219474],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9979128,0.001254115,0.000006621263,0.000219528,0.0000820522,0.00007608121,0.00008289111,0.000006311366,0.0003596004],"genre_scores_gemma":[0.999445,0.00006012382,0.00003726189,0.00003635878,0.0002010095,0.000001445878,0.000005428184,0.00003624825,0.0001771364],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01567478,"threshold_uncertainty_score":0.8788473,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01936516849004088,"score_gpt":0.196998149021621,"score_spread":0.1776329805315802,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}