{"id":"W1982387136","doi":"10.1021/om0504250","title":"Addition of a Cyclopropyl Alkyne to Tetramesityldisilene:  Evidence for a Biradical Intermediate and Formation of a Stable 1,2-Disilacyclohepta-3,4-diene","year":2005,"lang":"en","type":"article","venue":"Organometallics","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":34,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Chemistry; Alkyne; Diene; Radical; Photochemistry; Medicinal chemistry; Polymer chemistry; Computational chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002860103,0.0002451289,0.0005171633,0.0002315227,0.00007661084,0.00004793345,0.0003153301,0.0001411104,0.00245353],"category_scores_gemma":[0.0007358063,0.0002392619,0.0001348031,0.0004520524,0.0001141363,0.0005636566,0.0001398697,0.0001013828,0.00001176899],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001071374,"about_ca_system_score_gemma":0.00007799867,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001055321,"about_ca_topic_score_gemma":0.0000187493,"domain_scores_codex":[0.998173,0.00002022283,0.0008111077,0.0003648024,0.0003381588,0.0002926974],"domain_scores_gemma":[0.9983722,0.0003427733,0.0004369232,0.0004066845,0.0002584855,0.00018291],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001493155,0.0003033339,0.0008131501,0.0005344611,0.0000673023,4.28601e-7,0.0007415097,0.00001314839,0.9675452,0.0003452539,0.0001642776,0.02932269],"study_design_scores_gemma":[0.001014103,0.000231395,0.01071671,0.0004569967,0.0001839048,0.00002040154,0.0003427849,0.002072138,0.9641993,0.0001834062,0.0201267,0.0004521428],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9875812,0.0002954117,0.01057588,0.0006075592,0.00005127295,0.0002622886,0.0002969072,0.0000545459,0.0002749348],"genre_scores_gemma":[0.9922466,0.0003516123,0.006446714,0.0001128185,0.0001679194,0.00005847384,0.0001165859,0.00004695176,0.0004523342],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02887055,"threshold_uncertainty_score":0.9984584,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03646285837041333,"score_gpt":0.2753760584162623,"score_spread":0.238913200045849,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}