{"id":"W1982465438","doi":"10.1021/ja105588v","title":"Catalytic C−H Bond Stannylation: A New Regioselective Pathway to C−Sn Bonds via C−H Bond Functionalization","year":2010,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":99,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor","funders":"","keywords":"Chemistry; Regioselectivity; Surface modification; Catalysis; Combinatorial chemistry; Organic chemistry; Stereochemistry; Physical chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004898257,0.0002693505,0.0004467393,0.00004927318,0.0001848541,0.00007459056,0.0005306287,0.0001508437,0.0004232171],"category_scores_gemma":[0.001020135,0.0002128105,0.0005675373,0.001189542,0.0003094959,0.0002049213,0.0001618656,0.0008919002,0.00001575344],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000528971,"about_ca_system_score_gemma":0.0006998094,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00008066906,"about_ca_topic_score_gemma":0.00001019779,"domain_scores_codex":[0.9976475,0.0000258545,0.0007090087,0.000333811,0.0009604587,0.0003233422],"domain_scores_gemma":[0.9969215,0.0003615718,0.001169582,0.0005122022,0.0006495729,0.0003855625],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001463878,0.00009105715,0.001344613,0.00001923332,0.0001668909,0.000001412062,0.000537864,0.0001675014,0.9008757,0.0004121125,0.09017421,0.006063016],"study_design_scores_gemma":[0.001115361,0.00009269736,0.002238351,0.00006053553,0.0002166141,0.0004900525,0.0005393699,0.0008024487,0.8308622,0.005732317,0.1573703,0.0004797948],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8342278,0.0001254496,0.1474885,0.009818692,0.001174647,0.0002561551,0.00006482555,0.0001169927,0.006726927],"genre_scores_gemma":[0.9151642,0.00002031805,0.06292434,0.005351745,0.005499038,0.00001832616,0.00007576065,0.0001451408,0.01080113],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.08456418,"threshold_uncertainty_score":0.8678159,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01308806482238178,"score_gpt":0.2695642431511022,"score_spread":0.2564761783287204,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}