{"id":"W1982549777","doi":"10.1080/10426500490427646","title":"1,2,4,6-THIATRIAZINYLS: STABLE FREE RADICALS WITH WELL-DEFINED EPR SPECTRA","year":2004,"lang":"en","type":"article","venue":"Phosphorus, sulfur, and silicon and the related elements","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":9,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Lethbridge","funders":"","keywords":"Hyperfine coupling; Electron paramagnetic resonance; Hyperfine structure; Spectral line; Gaussian; Ring (chemistry); Coupling (piping); Coupling constant; Spectrometer; Chemistry; Character (mathematics); Atomic physics; Physics; Materials science; Nuclear magnetic resonance; Computational chemistry; Quantum mechanics; Mathematics; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003226413,0.0002292176,0.0002239863,0.0001496489,0.0002189772,0.0002153324,0.0003234516,0.0002937658,0.002876213],"category_scores_gemma":[0.0003736184,0.0001103699,0.0001191857,0.0001792611,0.0002605777,0.0003198269,0.0002083184,0.0004334968,0.0003944818],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00026631,"about_ca_system_score_gemma":0.0001904333,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002463465,"about_ca_topic_score_gemma":0.0002631063,"domain_scores_codex":[0.999911,0.00002509714,0.000005466519,0.0000154123,0.00002279024,0.00002023304],"domain_scores_gemma":[0.9998041,0.00004306907,0.00005178916,0.00003220834,0.00003047697,0.00003836434],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006406761,0.0001141196,0.000664618,0.0002318471,0.0000394347,0.0001926916,0.0001961444,0.005641608,0.9840186,0.002279084,0.0003761353,0.005605092],"study_design_scores_gemma":[0.0002444169,0.003016989,0.002864246,0.00001665184,0.00003415269,0.0002048671,0.000109875,0.01708128,0.9690437,0.001118563,0.006230696,0.0000345765],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.995847,0.000528941,0.002316223,0.00005504883,0.00002443394,0.00002550663,0.0001064273,0.00004007524,0.001056317],"genre_scores_gemma":[0.9950867,0.0003172035,0.00238795,0.00001885993,0.000006221284,0.00003411599,0.0001911555,0.00001647723,0.001941273],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002876213,"threshold_uncertainty_score":0.009621918,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005154181744218784,"score_gpt":0.2067195517164871,"score_spread":0.2015653699722683,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}