{"id":"W1982768851","doi":"10.1021/om700550x","title":"Hemilabile Pincer-Type Hydride Complexes of Iridium","year":2007,"lang":"en","type":"article","venue":"Organometallics","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":62,"is_retracted":false,"has_abstract":true,"ca_institutions":"Wilfrid Laurier University; University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Cyclohexanone; Acetophenone; Iridium; Medicinal chemistry; Ligand (biochemistry); Pincer ligand; Toluene; Yield (engineering); Hydride; Pincer movement; Catalysis; Ketone; Ethyl diazoacetate; Transfer hydrogenation; Rhodium; Chloride; Organic chemistry; Receptor","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001224043,0.0003894839,0.00031166,0.0001318898,0.0001695719,0.0003688719,0.000608253,0.0003123239,0.002158975],"category_scores_gemma":[0.0002062667,0.0002042335,0.00008755458,0.000128001,0.0003060799,0.0003294186,0.0006035471,0.0003827089,0.0004239888],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005177046,"about_ca_system_score_gemma":0.0001698295,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003565231,"about_ca_topic_score_gemma":0.0006229004,"domain_scores_codex":[0.9998866,0.00002256067,0.000004021138,0.00002226168,0.00002333156,0.00004106434],"domain_scores_gemma":[0.9999433,0.00001136421,0.00001295691,0.000007906742,0.000005670149,0.00001879866],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006296693,0.00007648582,0.0002784267,0.0003684128,0.00002665391,0.0003135323,0.0001246301,0.001620853,0.977697,0.006917372,0.00101882,0.01092797],"study_design_scores_gemma":[0.0001269039,0.0004156042,0.0003913475,0.0000118919,0.0000191142,0.0002476414,0.00003690618,0.002074832,0.9852008,0.0004428174,0.01100928,0.00002289877],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9573351,0.001546948,0.01683472,0.000265172,0.00009936819,0.0001608561,0.0002121062,0.0006102023,0.02293544],"genre_scores_gemma":[0.9909083,0.000432501,0.00344639,0.00007737466,0.00001076414,0.00005136872,0.0001188221,0.00003506612,0.004919356],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002158975,"threshold_uncertainty_score":0.007222474,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0131436861277344,"score_gpt":0.2507523251551806,"score_spread":0.2376086390274462,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}