{"id":"W1983295029","doi":"10.1002/chem.201002913","title":"Characterising Lone‐Pair Activity of Lead(II) by 207Pb Solid‐State NMR Spectroscopy: Coordination Polymers of [N(CN)2]− and [Au(CN)2]− with Terpyridine Ancillary Ligands","year":2011,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Magnetism in coordination complexes","field":"Materials Science","cited_by":55,"is_retracted":false,"has_abstract":true,"ca_institutions":"Simon Fraser University; University of Manitoba","funders":"","keywords":"Chemistry; Terpyridine; Crystallography; Lone pair; Chemical shift; Nuclear magnetic resonance spectroscopy; NMR spectra database; Coordination complex; Ligand (biochemistry); Coordination sphere; Coordination number; Spectroscopy; Molecule; Stereochemistry; Physical chemistry; Spectral line; Metal; Crystal structure; Ion; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.002823272,0.001161729,0.001447245,0.0003729679,0.0009161754,0.0004032197,0.001228114,0.000239482,0.0005296722],"category_scores_gemma":[0.0004134196,0.00113089,0.0003334837,0.0007654378,0.001267757,0.001534481,0.0006814441,0.00116802,0.00004432396],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003986562,"about_ca_system_score_gemma":0.0005048928,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003733392,"about_ca_topic_score_gemma":0.000002843869,"domain_scores_codex":[0.9931076,0.0006840648,0.001918798,0.001377597,0.001424695,0.001487227],"domain_scores_gemma":[0.994872,0.0002366069,0.002238467,0.001088718,0.0007924564,0.000771746],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0008754116,0.0005694855,0.001861584,0.000569145,0.0001542889,0.0002365091,0.004533601,0.0005813072,0.9811534,0.000003318473,0.001867822,0.007594152],"study_design_scores_gemma":[0.00274187,0.0009978472,0.002798903,0.0007129994,0.0002012262,0.001496756,0.0008212863,0.008989844,0.9797688,0.00005168953,0.0003236819,0.001095096],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9935291,0.0004411186,0.002783158,0.0003936685,0.0001473455,0.0004618639,0.0004049301,0.0002069499,0.001631824],"genre_scores_gemma":[0.9969379,0.0003332195,0.001295681,0.0001272885,0.0006564336,0.00001711873,0.00008933956,0.0002501491,0.0002929197],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008408538,"threshold_uncertainty_score":0.9991141,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01269012556818225,"score_gpt":0.2116730942772464,"score_spread":0.1989829687090641,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}