{"id":"W1983465293","doi":"10.1021/ic049840v","title":"Emitting-State Displacements in Ligand-Centered Vibrational Modes in the <i>trans-</i>[OsO<sub>2</sub>(NCS)<sub>4</sub>]<sup>2</sup><sup>-</sup> Complex Determined from Near-Infrared Luminescence Spectroscopy","year":2004,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Magnetism in coordination complexes","field":"Materials Science","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal; McGill University","funders":"","keywords":"Chemistry; Luminescence; Ligand (biochemistry); Raman spectroscopy; Spectral line; Ground state; Molecular vibration; Infrared; Molecular physics; Normal mode; Infrared spectroscopy; Analytical Chemistry (journal); Crystallography; Atomic physics; Molecule; Physics; Optics; Vibration","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001125283,0.0002276286,0.0001935912,0.0001325807,0.0001256288,0.0003719022,0.0004546023,0.0002694177,0.001391934],"category_scores_gemma":[0.0003487615,0.0001525853,0.0001154377,0.0001398829,0.0003007924,0.0002690597,0.000245952,0.0002749982,0.0001517272],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000313859,"about_ca_system_score_gemma":0.0001476688,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008650392,"about_ca_topic_score_gemma":0.0009614877,"domain_scores_codex":[0.9998734,0.00001297832,0.00001219057,0.00002897679,0.00005405446,0.00001850225],"domain_scores_gemma":[0.9998819,0.00001939365,0.00004418356,0.000007179176,0.00003086896,0.00001640945],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009518264,0.000007341307,0.0007437112,0.00003941959,0.000006529662,0.00001618078,0.00003589057,0.000161371,0.9978263,0.00009834604,0.00003641206,0.0009332815],"study_design_scores_gemma":[0.00001213679,0.000133484,0.00508014,0.000003809029,0.00001355732,0.00008117304,0.0000836593,0.001444076,0.9922718,0.00004609513,0.0008199465,0.00001002829],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9983357,0.00009491633,0.0008011824,0.00002118672,0.000003873263,0.000004703566,0.0000841318,0.00003444934,0.0006198357],"genre_scores_gemma":[0.9979725,0.00007187385,0.001008155,0.00001793403,0.000001435587,0.00001118059,0.0002401972,0.0000214506,0.0006552816],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001391934,"threshold_uncertainty_score":0.004656553,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01364999881495673,"score_gpt":0.235054668753052,"score_spread":0.2214046699380952,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}