{"id":"W1983499482","doi":"10.1002/chin.200943032","title":"ChemInform Abstract: One‐Pot Curtius Rearrangement Processes from Carboxylic Acids.","year":2009,"lang":"en","type":"article","venue":"ChemInform","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Curtius rearrangement; Chemistry; Service (business); Combinatorial chemistry; Stereochemistry; Business; Marketing","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004788901,0.001576644,0.0006989228,0.000847037,0.0008305308,0.000701519,0.001275892,0.0007103193,0.02530702],"category_scores_gemma":[0.000608999,0.0004035161,0.0005932587,0.0009462165,0.0006055456,0.001743134,0.001501636,0.001988173,0.009534478],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000799469,"about_ca_system_score_gemma":0.001520814,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001445111,"about_ca_topic_score_gemma":0.002105695,"domain_scores_codex":[0.9995188,0.00005466285,0.0000237609,0.0001098222,0.0001088032,0.0001842391],"domain_scores_gemma":[0.9998428,0.00002924842,0.00002673306,0.00002582799,0.00002590904,0.00004960004],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.002058681,0.000664163,0.0003123271,0.00499414,0.0004594069,0.002329616,0.001359003,0.003909967,0.601509,0.05288941,0.1396845,0.1898297],"study_design_scores_gemma":[0.0003611869,0.001291351,0.0007727136,0.000256569,0.0001070736,0.001146888,0.000180796,0.002917207,0.7500277,0.007108689,0.2356476,0.0001822144],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.3005566,0.03102275,0.1995475,0.004915529,0.008424177,0.002029335,0.01043311,0.01147107,0.4315999],"genre_scores_gemma":[0.8301572,0.02546594,0.02447693,0.001755815,0.0005449572,0.0006262892,0.004971911,0.001162234,0.1108387],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.02530702,"threshold_uncertainty_score":0.08466047,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01638038738250343,"score_gpt":0.2265287523477801,"score_spread":0.2101483649652767,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}