{"id":"W1983668219","doi":"10.1016/j.ica.2007.10.041","title":"Pt(II) compounds with sulfoxide ligands and crystal structures of complexes of the types I(R2SO)Pt(μ-I)2Pt(R2SO)I and trans-Pt(R2SO)(L)X2 (L = amine, pyridine and pyrimidine)","year":2007,"lang":"en","type":"article","venue":"Inorganica Chimica Acta","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":18,"is_retracted":false,"has_abstract":false,"ca_institutions":"Université du Québec à Montréal","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Pyridine; Amine gas treating; Crystal structure; Molecule; Ligand (biochemistry); Pyrimidine; Crystallography; Stereochemistry; Sulfoxide; Hydrogen bond; Medicinal chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009808303,0.0002200499,0.0003423189,0.0002185623,0.000386132,0.0005169075,0.0006785237,0.0004663668,0.003034166],"category_scores_gemma":[0.0003138132,0.0003071481,0.00009669274,0.0005821583,0.0002861371,0.0002399796,0.0002215513,0.0005682652,0.0002647011],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006441975,"about_ca_system_score_gemma":0.0003436528,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00289569,"about_ca_topic_score_gemma":0.002261393,"domain_scores_codex":[0.99991,0.0000115749,0.000008394552,0.00001802955,0.0000363773,0.00001574921],"domain_scores_gemma":[0.999908,0.00002193826,0.00002971229,0.000009957905,0.00001404775,0.0000163904],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001514714,0.0001344419,0.002446564,0.0008519358,0.00008121583,0.0004395899,0.0003823754,0.004483313,0.9632919,0.007571037,0.007438729,0.01136405],"study_design_scores_gemma":[0.0007644484,0.000636392,0.007528092,0.00003296,0.0001071042,0.001401956,0.0004197339,0.008003848,0.9529093,0.0012529,0.02690772,0.00003545739],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9863381,0.00118167,0.001668819,0.0003452389,0.00003431596,0.00003861472,0.001677032,0.0001916104,0.008524557],"genre_scores_gemma":[0.9904383,0.0005536799,0.003141437,0.0000611678,0.00001269716,0.00006960061,0.002526677,0.00004410464,0.003152271],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003034166,"threshold_uncertainty_score":0.01015031,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01684065105008758,"score_gpt":0.2274649003060711,"score_spread":0.2106242492559835,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}