{"id":"W1983858757","doi":"10.1021/ic991238v","title":"Polylithiated Tetraaminosilanes:  Synthesis and Characterization of (Et<sub>2</sub>O·Li)<sub>4</sub>[Si(Nnaph)<sub>4</sub>] and X-ray Structure of {THF·Li<sub>3</sub>[Si(N<sup>i</sup>Pr)<sub>3</sub>(NH<sup>i</sup>Pr)]}<sub>2</sub>","year":2000,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"","keywords":"Chemistry; Monoclinic crystal system; Diethyl ether; Dimer; Lithium (medication); Crystal structure; Crystallography; X-ray; X-ray crystallography; Characterization (materials science); Silicon; Medicinal chemistry; Stereochemistry; Diffraction; Nanotechnology; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts","scholarly_communication","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow","research_integrity"],"category_scores_codex":[0.001338031,0.004700581,0.005222132,0.001111787,0.001338548,0.001153904,0.003080688,0.004243828,0.001511696],"category_scores_gemma":[0.001673158,0.005290248,0.001445347,0.003757443,0.002005866,0.002192871,0.001366475,0.003410023,0.0002621356],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001290841,"about_ca_system_score_gemma":0.0016561,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006639503,"about_ca_topic_score_gemma":0.000057562,"domain_scores_codex":[0.9804989,0.000660602,0.006174929,0.005360546,0.003566175,0.003738844],"domain_scores_gemma":[0.9857883,0.001839858,0.003999519,0.00457723,0.001671067,0.002124006],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0009261029,0.001820119,0.004773051,0.003771121,0.00192694,0.000177977,0.002781107,0.0001231125,0.9554751,0.00002460813,0.0004938096,0.02770695],"study_design_scores_gemma":[0.004356766,0.0002704301,0.01878634,0.001937462,0.001807784,0.001024897,0.001543075,0.001640482,0.9630428,0.00015243,0.0005681841,0.004869362],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9896226,0.001474245,0.000125036,0.0006593828,0.000469115,0.001531597,0.00434141,0.001210267,0.0005663785],"genre_scores_gemma":[0.983608,0.007806887,0.00007696556,0.0007053144,0.001875948,0.0002516094,0.004263203,0.001316544,0.00009553281],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02283759,"threshold_uncertainty_score":0.9999616,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006650146239921561,"score_gpt":0.1907336620221747,"score_spread":0.1840835157822532,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}