{"id":"W1983858757","doi":"10.1021/ic991238v","title":"Polylithiated Tetraaminosilanes:  Synthesis and Characterization of (Et<sub>2</sub>O·Li)<sub>4</sub>[Si(Nnaph)<sub>4</sub>] and X-ray Structure of {THF·Li<sub>3</sub>[Si(N<sup>i</sup>Pr)<sub>3</sub>(NH<sup>i</sup>Pr)]}<sub>2</sub>","year":2000,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"","keywords":"Chemistry; Monoclinic crystal system; Diethyl ether; Dimer; Lithium (medication); Crystal structure; Crystallography; X-ray; X-ray crystallography; Characterization (materials science); Silicon; Medicinal chemistry; Stereochemistry; Diffraction; Nanotechnology; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0000530387,0.00017039,0.00006666196,0.0001244859,0.00009060917,0.000107514,0.0001510925,0.0001196078,0.002018381],"category_scores_gemma":[0.00009993632,0.00009120854,0.00007231776,0.0001386942,0.0001329368,0.0001366957,0.0001056126,0.0002365624,0.0006805498],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001278445,"about_ca_system_score_gemma":0.0001318419,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004363968,"about_ca_topic_score_gemma":0.001386274,"domain_scores_codex":[0.9999483,0.000003022203,0.000003697418,0.00001120636,0.00002486861,0.000008863557],"domain_scores_gemma":[0.9998984,0.00001543337,0.00003298434,0.00001299224,0.00002177244,0.00001832518],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002032667,0.00000373013,0.00007121835,0.00001132961,0.000001159742,0.00001568563,0.000006983276,0.00002819808,0.9987246,0.00001594423,0.00001630516,0.001084349],"study_design_scores_gemma":[0.000004272343,0.00006958045,0.001929856,0.000002105269,0.000003496188,0.00007361611,0.000008669504,0.0001635828,0.9956871,0.000009420067,0.002046343,0.000002046088],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9892541,0.0007196849,0.005053219,0.00005328528,0.00001620907,0.00003271766,0.0006666949,0.0001588765,0.004045296],"genre_scores_gemma":[0.9774758,0.0008015929,0.009006452,0.00006536483,0.00001295861,0.00006197766,0.002054942,0.00008527108,0.01043571],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002018381,"threshold_uncertainty_score":0.006752193,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006650146239921561,"score_gpt":0.1907336620221747,"score_spread":0.1840835157822532,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}