{"id":"W1984227759","doi":"10.1139/v06-140","title":"The photochemistry of ring-substituted cinnamyl acetates","year":2006,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Isomerization; Photochemistry; Aryl; Cyclohexane; Alkene; Excited state; Singlet state; Methanol; Quantum yield; Regioselectivity; Propenyl; Ring (chemistry); Medicinal chemistry; Fluorescence; Organic chemistry; Catalysis","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001142525,0.0003174355,0.0001016633,0.0001694474,0.0001465474,0.0001503559,0.0002174631,0.0002476507,0.002059967],"category_scores_gemma":[0.0001808142,0.0001071087,0.0002019185,0.0001739198,0.0001794034,0.0002265499,0.0001114694,0.0003089881,0.0002907765],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004391347,"about_ca_system_score_gemma":0.0001723496,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001327223,"about_ca_topic_score_gemma":0.002194246,"domain_scores_codex":[0.9998965,0.00001252123,0.000003460748,0.00001947311,0.00002543624,0.00004257189],"domain_scores_gemma":[0.9999148,0.00002430803,0.00002283476,0.000009532025,0.00001499765,0.00001344587],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008677974,0.000007552375,0.000118349,0.00002935775,0.000004241386,0.00005077788,0.0000201365,0.0001269725,0.9980672,0.00009085224,0.00002385067,0.001373997],"study_design_scores_gemma":[0.000003780059,0.0001058631,0.001192545,0.000001880381,0.000003560851,0.00005144036,0.000009305282,0.0001887527,0.9979025,0.00001954084,0.0005173094,0.000003439118],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.994719,0.0007651883,0.0009876337,0.00004124346,0.00001737817,0.00001517983,0.000172597,0.00003213496,0.003249539],"genre_scores_gemma":[0.9966821,0.0004873271,0.0007836285,0.00002672284,0.000004911931,0.00000963834,0.0001596061,0.00001262907,0.001833417],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002059967,"threshold_uncertainty_score":0.006891251,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005515898733438097,"score_gpt":0.1997058325893167,"score_spread":0.1941899338558785,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}