{"id":"W1984382754","doi":"10.1021/je060344q","title":"Comparison of Headspace and Gas-Stripping Techniques for Measuring the Air−Water Partititioning of Normal Alkanols (C4 to C10):  Effect of Temperature, Chain Length, and Adsorption to the Water Surface","year":2006,"lang":"en","type":"article","venue":"Journal of Chemical & Engineering Data","topic":"Atmospheric chemistry and aerosols","field":"Earth and Planetary Sciences","cited_by":23,"is_retracted":false,"has_abstract":true,"ca_institutions":"The Scarborough Hospital; University of Toronto","funders":"","keywords":"Chemistry; Adsorption; Stripping (fiber); Partition coefficient; Evaporation; Water vapor; Analytical Chemistry (journal); Inert gas; Solubility; Bubble; Thermodynamics; Chromatography; Physical chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001167042,0.001111149,0.0004237973,0.0008146014,0.0003830941,0.0005230084,0.0008266026,0.0006649817,0.000494901],"category_scores_gemma":[0.001870824,0.0006514803,0.0006593129,0.000626005,0.0006849209,0.0006839116,0.0005689673,0.0009933988,0.0003215141],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000406031,"about_ca_system_score_gemma":0.0006241389,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002976345,"about_ca_topic_score_gemma":0.006059877,"domain_scores_codex":[0.9985082,0.0002560088,0.00008654744,0.0002895996,0.0006846019,0.0001751751],"domain_scores_gemma":[0.9978218,0.00090739,0.0003679032,0.0002021766,0.0005864342,0.0001142551],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001862334,0.00003177663,0.001243574,0.0001362163,0.00004172866,0.00002516192,0.00007449758,0.0001513755,0.994275,0.00004575267,0.00003548389,0.003753211],"study_design_scores_gemma":[0.000003869881,0.0001230245,0.003489789,0.000003758921,0.00002381675,0.00005612039,0.00003775637,0.0009487873,0.995044,0.00001640346,0.0002402268,0.00001237737],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9574312,0.00352598,0.03615641,0.0001043615,0.0001227861,0.0001313522,0.0007777052,0.0002930661,0.001457133],"genre_scores_gemma":[0.9506606,0.003643491,0.04174089,0.0001714042,0.0000566118,0.0002480543,0.001108286,0.0001186597,0.002251993],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002976345,"threshold_uncertainty_score":0.006172001,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01308556870239405,"score_gpt":0.2334510105065243,"score_spread":0.2203654418041302,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}