{"id":"W1984382754","doi":"10.1021/je060344q","title":"Comparison of Headspace and Gas-Stripping Techniques for Measuring the Air−Water Partititioning of Normal Alkanols (C4 to C10):  Effect of Temperature, Chain Length, and Adsorption to the Water Surface","year":2006,"lang":"en","type":"article","venue":"Journal of Chemical & Engineering Data","topic":"Atmospheric chemistry and aerosols","field":"Earth and Planetary Sciences","cited_by":23,"is_retracted":false,"has_abstract":true,"ca_institutions":"The Scarborough Hospital; University of Toronto","funders":"","keywords":"Chemistry; Adsorption; Stripping (fiber); Partition coefficient; Evaporation; Water vapor; Analytical Chemistry (journal); Inert gas; Solubility; Bubble; Thermodynamics; Chromatography; Physical chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0007185475,0.00009934158,0.0002621514,0.000008292422,0.00003270988,0.00002071845,0.0002305573,0.00004793814,0.000009779038],"category_scores_gemma":[0.0001002493,0.00004646278,0.00003485501,0.00005900745,0.00003597603,0.0001420653,0.00005197592,0.0001452784,1.884283e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000004017836,"about_ca_system_score_gemma":0.000006970964,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004708296,"about_ca_topic_score_gemma":0.000004256436,"domain_scores_codex":[0.9992122,0.00001888415,0.0003410468,0.000103002,0.0001670243,0.0001578076],"domain_scores_gemma":[0.9994491,0.0001911944,0.00009045881,0.000160015,0.00005025631,0.00005892172],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008547357,0.000007134411,0.005575883,0.0001515758,0.00001850406,3.775976e-7,0.0001058843,0.0249766,0.9684433,9.623823e-7,0.0002276468,0.0004065932],"study_design_scores_gemma":[0.000153254,0.0001292344,0.0008878258,0.0002174075,0.00002885028,0.00001944149,0.00002245641,0.005093151,0.9927616,0.000005152907,0.0006156213,0.00006607006],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.996991,0.0002735862,0.00197557,0.0005035228,0.00003383953,0.0001521199,0.00005588726,0.000005985784,0.000008459424],"genre_scores_gemma":[0.9960852,0.00001047837,0.003721401,0.00001251513,0.0001166231,8.659815e-7,0.00004371449,0.000003771876,0.000005445688],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02431818,"threshold_uncertainty_score":0.1894697,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01308556870239405,"score_gpt":0.2334510105065243,"score_spread":0.2203654418041302,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}