{"id":"W1984595973","doi":"10.1021/ol900292r","title":"Ketonitrones via Cope-Type Hydroamination of Allenes","year":2009,"lang":"en","type":"article","venue":"Organic Letters","topic":"Oxidative Organic Chemistry Reactions","field":"Chemistry","cited_by":53,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Hydroamination; Chemistry; Hydroxylamine; Yield (engineering); Computational chemistry; Aqueous solution; Catalysis; Organic chemistry; Thermodynamics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001590066,0.0003693815,0.0001687493,0.0001412118,0.0001446804,0.0001557836,0.0002752364,0.0001944711,0.002188167],"category_scores_gemma":[0.0002064089,0.0001528591,0.0002084368,0.00009322297,0.0001864192,0.000461893,0.0003554566,0.0004139314,0.0006475331],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001136043,"about_ca_system_score_gemma":0.0001358536,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001819348,"about_ca_topic_score_gemma":0.0005531025,"domain_scores_codex":[0.9999285,0.00001010394,0.000007346488,0.00001449131,0.00001755745,0.00002201277],"domain_scores_gemma":[0.9999177,0.00001280419,0.00002571015,0.00001493591,0.00001476308,0.00001402055],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002166631,0.00005562457,0.0005728484,0.0005509247,0.00003654213,0.000941527,0.0002719041,0.001389146,0.9766945,0.004450049,0.0005122334,0.014308],"study_design_scores_gemma":[0.00003840416,0.0005689185,0.001050886,0.00002261767,0.00001958691,0.0006377255,0.00004869611,0.001039143,0.9872808,0.0004970527,0.008780251,0.00001595657],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9682532,0.001568949,0.01583769,0.0001770891,0.0001087949,0.0001044518,0.0003537203,0.0001791593,0.01341684],"genre_scores_gemma":[0.9914297,0.001305924,0.004339211,0.00004887371,0.00001352986,0.00003823224,0.0002100222,0.00002125533,0.002593224],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002188167,"threshold_uncertainty_score":0.007320166,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00786653636973812,"score_gpt":0.2210517321421547,"score_spread":0.2131851957724166,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}