{"id":"W1984620680","doi":"10.1016/j.chroma.2012.10.052","title":"Gas chromatographic retention of alkyl phosphates on ionic liquid stationary phases","year":2012,"lang":"en","type":"article","venue":"Journal of Chromatography A","topic":"Analytical Chemistry and Chromatography","field":"Chemistry","cited_by":14,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Alberta","funders":"","keywords":"Chemistry; Alkyl; Chromatography; Elution; Phosphate; Ionic liquid; Selectivity; Homologous series; Gas chromatography; High-performance liquid chromatography; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0004713557,0.0003880749,0.0006956991,0.0005714873,0.0001408036,0.00003329989,0.0004400099,0.0002552126,0.001920104],"category_scores_gemma":[0.0001028178,0.0003340988,0.001328967,0.001053173,0.0003957551,0.000579512,0.00004126155,0.0004590738,0.000008501056],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003543471,"about_ca_system_score_gemma":0.00008667351,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000005638634,"about_ca_topic_score_gemma":3.816287e-7,"domain_scores_codex":[0.9969079,0.00005098551,0.001307732,0.0002360434,0.000935549,0.0005618122],"domain_scores_gemma":[0.9971232,0.0002805206,0.001386528,0.000416018,0.000357612,0.0004360513],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.002142209,0.004847858,0.08771601,0.001690646,0.002531665,0.0001034367,0.0005573742,0.00005827272,0.8869472,0.004786806,0.007370499,0.001248045],"study_design_scores_gemma":[0.002130404,0.0008136673,0.004239995,0.001213669,0.0005428895,0.0004585378,0.0007405216,0.00003843422,0.9834904,0.001550627,0.004259957,0.0005208779],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.985204,0.006737874,0.0001260223,0.0001009279,0.0001849613,0.00006087653,0.00004534985,0.00006130217,0.007478646],"genre_scores_gemma":[0.9977909,0.001118083,0.0004984659,0.00006721921,0.0004048951,0.000007758375,0.00003495828,0.00004263903,0.00003512464],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.09654325,"threshold_uncertainty_score":0.9999111,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01413731575959257,"score_gpt":0.246616234973328,"score_spread":0.2324789192137354,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}