{"id":"W1984635346","doi":"10.1063/1.1786920","title":"Isotope effects and Born-Oppenheimer breakdown in excited singlet states of the lithium dimer","year":2004,"lang":"en","type":"article","venue":"The Journal of Chemical Physics","topic":"Advanced Chemical Physics Studies","field":"Physics and Astronomy","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Waterloo; University of New Brunswick","funders":"","keywords":"Isotopomers; Chemistry; Atomic physics; Lithium (medication); Kinetic isotope effect; Excited state; Born–Oppenheimer approximation; Singlet state; Dimer; Rydberg formula; Resonance (particle physics); Molecular electronic transition; Deuterium; Physics; Ionization; Ion; Molecule","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002291352,0.0001715951,0.0001479322,0.0003853943,0.0002889178,0.0002060748,0.0003456365,0.0003026296,0.001408352],"category_scores_gemma":[0.000672898,0.0002007255,0.0001226091,0.0002774608,0.0004135086,0.0004673309,0.0004391207,0.0005256126,0.0002016522],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003366783,"about_ca_system_score_gemma":0.00009768103,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000521148,"about_ca_topic_score_gemma":0.0006919925,"domain_scores_codex":[0.9999038,0.0000177606,0.000004537848,0.00002111885,0.00002954686,0.00002323038],"domain_scores_gemma":[0.9997995,0.00008640396,0.0000411717,0.00002285953,0.00002416139,0.00002583784],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"theoretical_or_conceptual","study_design_scores_codex":[0.0004879493,0.00004284335,0.006413789,0.00003557784,0.00001253653,0.0002043601,0.0003369575,0.002637338,0.977128,0.002038814,0.00005125448,0.01061046],"study_design_scores_gemma":[0.00002333001,0.0002950848,0.01271403,0.000006382023,0.00001019804,0.0003177103,0.0001849081,0.01970479,0.9647535,0.001392214,0.0005772192,0.00002055873],"study_design_candidate":"theoretical_or_conceptual","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9982458,0.0001439718,0.001159579,0.00001975152,0.000001403164,0.000001658505,0.00001497698,0.00001852619,0.000394322],"genre_scores_gemma":[0.9989373,0.00007600926,0.0005783425,0.000008851252,0.0000012603,0.000003002523,0.00003971364,0.000008846543,0.0003466475],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001408352,"threshold_uncertainty_score":0.00471139,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005816945298349878,"score_gpt":0.2272457007478956,"score_spread":0.2214287554495457,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}