{"id":"W1984751438","doi":"10.1021/jo015910t","title":"Structural and Electronic Characteristics of Thienyl(aryl)iodonium Triflates","year":2002,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Oxidative Organic Chemistry Reactions","field":"Chemistry","cited_by":28,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Aryl; Trifluoromethanesulfonate; Moiety; Counterion; Cationic polymerization; Chemistry; Thiophene; HOMO/LUMO; Polar effect; Polymer chemistry; Medicinal chemistry; Stereochemistry; Molecule; Ion; Organic chemistry; Catalysis; Alkyl","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002518378,0.0002550244,0.000434803,0.00002220278,0.0001228718,0.00002773588,0.0005024571,0.0001753683,0.01215436],"category_scores_gemma":[0.0003374631,0.0001891877,0.0001205684,0.0002092498,0.0002631421,0.00009909756,0.000111043,0.0008991847,0.000007281079],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001666532,"about_ca_system_score_gemma":0.0001066684,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00000299256,"about_ca_topic_score_gemma":6.386113e-7,"domain_scores_codex":[0.9984388,0.00001518119,0.0007103239,0.0001548685,0.0003455699,0.0003352156],"domain_scores_gemma":[0.997988,0.0002607113,0.000973506,0.0004200511,0.0002224063,0.0001353041],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005312628,0.00005067221,0.001290811,0.0001705901,0.000165047,0.000006954622,0.0003646363,6.198057e-7,0.9968174,0.00000476283,0.0002466987,0.0008286606],"study_design_scores_gemma":[0.0007904399,0.00002903994,0.0006887218,0.0000753597,0.0002370305,0.002151275,0.0005372807,0.0001057769,0.9942924,0.0001180652,0.0007842405,0.0001903428],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9956151,0.00148701,0.00001213192,0.0004771968,0.00005258303,0.00002676274,0.00002311864,0.00002139244,0.00228476],"genre_scores_gemma":[0.996813,0.00096653,0.00003663055,0.00001783442,0.0004091822,4.681595e-7,0.000005062844,0.00003960278,0.0017117],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01214708,"threshold_uncertainty_score":0.9887487,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009035483619622822,"score_gpt":0.2017870425665321,"score_spread":0.1927515589469093,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}