{"id":"W1984781295","doi":"10.1021/ma002082h","title":"Volumetric Studies of Aqueous Polymer Solutions Using Pressure Perturbation Calorimetry:  A New Look at the Temperature-Induced Phase Transition of Poly(<i>N</i>-isopropylacrylamide) in Water and D<sub>2</sub>O","year":2001,"lang":"en","type":"article","venue":"Macromolecules","topic":"Hydrogels: synthesis, properties, applications","field":"Biochemistry, Genetics and Molecular Biology","cited_by":266,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Poly(N-isopropylacrylamide); Polymer; Aqueous solution; Phase transition; Lower critical solution temperature; Calorimetry; Chemistry; Thermodynamics; Polymer chemistry; Micelle; Differential scanning calorimetry; Transition temperature; Materials science; Physical chemistry; Organic chemistry; Copolymer","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000174735,0.0004590035,0.0002148634,0.0003010095,0.0001438413,0.0003012751,0.0004069306,0.0003572837,0.0004677258],"category_scores_gemma":[0.0004827535,0.0001842237,0.0001548292,0.0002422744,0.0005354735,0.0005517579,0.0003407383,0.0009376393,0.0001435837],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001855864,"about_ca_system_score_gemma":0.0001314797,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002331067,"about_ca_topic_score_gemma":0.0001737935,"domain_scores_codex":[0.9998277,0.00002990893,0.000008106419,0.00003576676,0.0000772475,0.00002119088],"domain_scores_gemma":[0.9997498,0.00009457814,0.00007218707,0.00001449577,0.00004984155,0.00001900588],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001198708,0.000008446345,0.0001415042,0.00002713347,0.000002537649,0.00001244323,0.00001776162,0.0001234208,0.9983595,0.00005051445,0.00001382763,0.001230945],"study_design_scores_gemma":[0.000002229496,0.00008676159,0.0009448666,0.000002472595,0.000004314134,0.00006552819,0.00001165239,0.001556061,0.9968387,0.00005034893,0.0004317521,0.000005253638],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9312819,0.003268891,0.0623905,0.0002075389,0.0000801198,0.000113431,0.0002238601,0.0003516598,0.002082009],"genre_scores_gemma":[0.9797714,0.001830055,0.0173311,0.0001067598,0.00005483511,0.00009670387,0.0001593882,0.00004390919,0.0006058448],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0004677258,"threshold_uncertainty_score":0.001564682,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02420175146389727,"score_gpt":0.2624096471256198,"score_spread":0.2382078956617225,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}