{"id":"W1984815017","doi":"10.1039/c4dt02407a","title":"Half sandwich ruthenium(<scp>ii</scp>) hydrides: hydrogenation of terminal, internal, cyclic and functionalized olefins","year":2014,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":24,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Ruthenium; Chemistry; Cationic polymerization; IMes; Medicinal chemistry; Catalysis; Stereochemistry; Organic chemistry; Carbene","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000233138,0.0002373045,0.0003313775,0.0003679295,0.0003081796,0.00003992667,0.0001938836,0.0001817661,0.0007119537],"category_scores_gemma":[0.000135139,0.0002397342,0.0002308721,0.00050864,0.0001284661,0.0001781905,0.00001582146,0.0002413204,0.00003621919],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006324908,"about_ca_system_score_gemma":0.00004100871,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001884995,"about_ca_topic_score_gemma":0.0001036589,"domain_scores_codex":[0.9983739,0.0000442811,0.0005241932,0.0003976717,0.0004103942,0.0002495239],"domain_scores_gemma":[0.9987732,0.0003249665,0.0002456075,0.0003577034,0.0001246444,0.0001738589],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001733766,0.002875937,0.005022384,0.001072405,0.002464603,0.00001525676,0.007447459,0.003304683,0.6784554,0.003712751,0.002141301,0.2933145],"study_design_scores_gemma":[0.002776751,0.0001238101,0.0006602951,0.0000970968,0.0006705827,0.0001349298,0.00102172,0.02421186,0.7015542,0.0007074524,0.267733,0.0003083692],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8691561,0.0003987481,0.09869283,0.000228945,0.000166556,0.0001054863,0.000124502,0.0001758066,0.03095106],"genre_scores_gemma":[0.9912766,0.0001887665,0.0002623389,0.0001004975,0.000090061,0.00005118651,0.0001656447,0.00003468766,0.007830194],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.2930061,"threshold_uncertainty_score":0.9776078,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009922498065863896,"score_gpt":0.2316420276677635,"score_spread":0.2217195296018996,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}