{"id":"W1984864396","doi":"10.1039/c0dt00698j","title":"Mono and dinuclear areneruthenium(<scp>ii</scp>) triazoles by 1,3-dipolar cycloadditions to a coordinated azide in ruthenium(<scp>ii</scp>) compounds","year":2010,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Click Chemistry and Applications","field":"Chemistry","cited_by":31,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Chemistry; Ruthenium; Cycloaddition; Azide; Triclinic crystal system; Hexamethylbenzene; Stereochemistry; Medicinal chemistry; Oxalate; Ligand (biochemistry); Acetylene; 1,2,3-Triazole; Crystal structure; Crystallography; Catalysis; Benzene; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts"],"consensus_categories":[],"category_scores_codex":[0.0002215107,0.0005937347,0.0005801261,0.0002397014,0.001540211,0.0001848558,0.0005977626,0.000589791,0.000287571],"category_scores_gemma":[0.0002359274,0.0006785149,0.0002486698,0.0008892443,0.0003222428,0.0003265469,0.00007373046,0.001529441,0.00009326784],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001173043,"about_ca_system_score_gemma":0.0001134121,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003970222,"about_ca_topic_score_gemma":0.0006174581,"domain_scores_codex":[0.9969832,0.00004224734,0.000807182,0.0009817859,0.0003439801,0.0008416587],"domain_scores_gemma":[0.9971369,0.0008863297,0.0002132773,0.0009344124,0.0001390339,0.0006900741],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001462636,0.0009941416,0.0002333889,0.00007289047,0.0001014794,0.000005192031,0.001899044,0.0001156665,0.9798248,0.0003352382,0.01527442,0.001129123],"study_design_scores_gemma":[0.001348821,0.00004435907,0.0003133477,0.00006666531,0.0001266187,0.00005516308,0.001548603,0.0003915921,0.6505184,0.0004473912,0.3449459,0.000193158],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9808032,0.0001907909,0.001720536,0.001153795,0.0001665372,0.0003771635,0.00487211,0.0004874426,0.01022841],"genre_scores_gemma":[0.9875156,0.0001840621,0.0005881711,0.0002068813,0.0002158767,0.000588158,0.001060375,0.0001141478,0.009526704],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.3296715,"threshold_uncertainty_score":0.9997597,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0080747303992481,"score_gpt":0.2291448431595212,"score_spread":0.2210701127602731,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}