{"id":"W1984974709","doi":"10.1021/om030559i","title":"Electrophilic Attack on [Cp*Cl(PPh<sub>3</sub>)Ru(CCHR)]:  Carbyne Formation vs Chloride Abstraction","year":2003,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":27,"is_retracted":false,"has_abstract":true,"ca_institutions":"Lakehead University; Saint Mary's University","funders":"","keywords":"Chemistry; Electrophile; Carbyne; Ruthenium; Steric effects; Medicinal chemistry; Yield (engineering); Ligand (biochemistry); Chloride; Stereochemistry; Carbene; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.0003744631,0.0006033606,0.000671268,0.0003196848,0.0003609374,0.0002008562,0.0004415852,0.0003170313,0.01172874],"category_scores_gemma":[0.0003770721,0.0006120431,0.000430018,0.000954086,0.00009040895,0.0005329841,0.00006602462,0.0005364674,0.001582638],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005580242,"about_ca_system_score_gemma":0.0001179907,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000009851012,"about_ca_topic_score_gemma":0.00004321512,"domain_scores_codex":[0.9967728,0.00005924756,0.0008273922,0.0007814841,0.0007514027,0.0008076865],"domain_scores_gemma":[0.9977651,0.0002058453,0.0004522381,0.001134542,0.0001526958,0.0002895925],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008302615,0.0004223324,0.00009570148,0.000142966,0.0002422015,0.00001903331,0.0001528791,0.00009560756,0.9836944,0.001507336,0.0002406575,0.01330389],"study_design_scores_gemma":[0.0005211662,0.00008197271,0.0005260853,0.00003081828,0.0002301135,0.00008757731,0.0001459828,0.00009938776,0.8889347,0.0003178639,0.1083855,0.0006388575],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9549768,0.0002571081,0.0002408155,0.0002494721,0.0002120937,0.0001728158,0.00004115284,0.0002714337,0.04357832],"genre_scores_gemma":[0.9957219,0.0006519976,0.00009747109,0.0001836287,0.0003629567,0.00005983531,0.0002795942,0.0001420151,0.002500625],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1081449,"threshold_uncertainty_score":0.9996331,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02081873028073381,"score_gpt":0.2269674502208879,"score_spread":0.2061487199401541,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}