{"id":"W1985173175","doi":"10.1021/ja037076q","title":"Thermal Activation of Hydrocarbon C−H Bonds Initiated by a Tungsten Allyl Complex","year":2003,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":41,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Chemistry; Tetramethylsilane; Neopentane; Mesitylene; Allene; Thermal decomposition; Stereochemistry; Cyclohexene; Hydrocarbon; Medicinal chemistry; Benzene; Molecule; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009671736,0.0002422523,0.0002221949,0.0001385173,0.0001521444,0.0002432468,0.000228993,0.0002649695,0.001548232],"category_scores_gemma":[0.000213658,0.0001475673,0.0001219112,0.0001314746,0.0002101797,0.0002572219,0.0002898136,0.0003884423,0.0002227574],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003148675,"about_ca_system_score_gemma":0.0001959527,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005010923,"about_ca_topic_score_gemma":0.001125322,"domain_scores_codex":[0.9998835,0.000009297313,0.000005457624,0.00002683297,0.00003552774,0.0000393022],"domain_scores_gemma":[0.9999222,0.00001775871,0.0000271938,0.000009796127,0.00001054879,0.00001261093],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008266245,0.00001235929,0.000110709,0.00005424652,0.000007180635,0.00003234475,0.00003307695,0.0001639131,0.9980786,0.0003483123,0.00005977085,0.001016782],"study_design_scores_gemma":[0.00001409419,0.00008976219,0.0004867177,0.000003210378,0.000004525524,0.00004055445,0.000009823081,0.001056682,0.9973699,0.00003947957,0.0008812381,0.000003962401],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9956976,0.0003260065,0.001672531,0.00004369612,0.00001421479,0.00003014525,0.00006883688,0.00004313708,0.002103729],"genre_scores_gemma":[0.9972647,0.0002021259,0.000918417,0.00001716043,0.000003529576,0.00002187614,0.0000851169,0.00001705886,0.001470048],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001548232,"threshold_uncertainty_score":0.005179346,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01843530325744086,"score_gpt":0.2393877730333967,"score_spread":0.2209524697759558,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}