{"id":"W1985446938","doi":"10.1039/c1dt10646e","title":"Homoleptic, heteroleptic and mixed-valent thallium and indium complexes of multidentate chalcogen-centred PCP-bridged ligands","year":2011,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":17,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"","keywords":"Homoleptic; Chemistry; Denticity; Thallium; Selenium; Molar ratio; Chalcogen; Adduct; Medicinal chemistry; Crystallography; Crystal structure; Ligand (biochemistry); Stereochemistry; Inorganic chemistry; Metal; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00007300182,0.0002459571,0.0004052443,0.0001314617,0.000169369,0.00003220221,0.0001586438,0.00009124631,0.004548545],"category_scores_gemma":[0.000007387113,0.0002434424,0.0001454475,0.0001417173,0.0002284974,0.0001300704,0.00002433441,0.0001502455,0.00001262198],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002417263,"about_ca_system_score_gemma":0.00001965059,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003880655,"about_ca_topic_score_gemma":0.0002060744,"domain_scores_codex":[0.998697,0.00002069137,0.0004146876,0.0003857498,0.0001980634,0.0002838326],"domain_scores_gemma":[0.9992089,0.00005557405,0.0001420052,0.0003610131,0.00004807063,0.0001844588],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000101106,0.0007463938,0.002719606,0.0004834136,0.0006559942,0.0000127864,0.005317838,0.000004504754,0.9619112,0.0001151215,0.00002053783,0.02791153],"study_design_scores_gemma":[0.001097608,0.00006207858,0.02503291,0.00006331383,0.0004782165,0.00005676454,0.001888361,0.0002248879,0.9693901,0.00008069155,0.001275955,0.0003491252],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9953577,0.000967827,0.0009160376,0.00005729337,0.00007461291,0.00009758906,0.0003092697,0.00006816083,0.002151495],"genre_scores_gemma":[0.9981069,0.0007080572,0.0002972827,0.00001473542,0.00002810898,0.00002681603,0.00003994927,0.00003369601,0.0007444537],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0275624,"threshold_uncertainty_score":0.9963614,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03319944443167916,"score_gpt":0.2183309237600595,"score_spread":0.1851314793283804,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}