{"id":"W1985490102","doi":"10.1255/ejms.583","title":"Mass Spectrometric Analysis of Chemical Warfare Agents and Their Degradation Products in Soil and Synthetic Samples","year":2003,"lang":"en","type":"article","venue":"European Journal of Mass Spectrometry","topic":"Pesticide Exposure and Toxicity","field":"Agricultural and Biological Sciences","cited_by":64,"is_retracted":false,"has_abstract":true,"ca_institutions":"Defence Research and Development Canada","funders":"","keywords":"Organosulfur compounds; Chemistry; Chemical Warfare Agents; Mass spectrometry; Electrospray ionization; Chromatography; Mass spectrum; Chemical ionization; DART ion source; Electrospray; Gas chromatography; Analytical Chemistry (journal); Sulfur; Electron ionization; Organic chemistry; Ionization; Ion","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000384893,0.0005222338,0.0003023994,0.001211528,0.0003603512,0.0002812543,0.0003441335,0.0005338625,0.00065097],"category_scores_gemma":[0.0006361172,0.0001182218,0.0002057701,0.0008383064,0.0003115824,0.0002830809,0.0002500132,0.0002743037,0.0002335499],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000275645,"about_ca_system_score_gemma":0.000483248,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001148474,"about_ca_topic_score_gemma":0.002266192,"domain_scores_codex":[0.9995618,0.00005136595,0.00003072981,0.000124644,0.0001847136,0.00004673267],"domain_scores_gemma":[0.9995812,0.00008443469,0.00008472168,0.0000204231,0.0001816788,0.00004759599],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001287448,0.00004870829,0.00258275,0.00009993225,0.00001897397,0.00009288674,0.00004176102,0.0001980913,0.989715,0.0000494602,0.00003454084,0.006988995],"study_design_scores_gemma":[0.00001573423,0.0007776986,0.02327237,0.00002317612,0.00004097945,0.0007686484,0.0001174139,0.003601944,0.9692704,0.0000846668,0.002006925,0.00002002072],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9695929,0.002278218,0.02461747,0.00004590076,0.00002980641,0.000193285,0.001536787,0.0002182774,0.001487514],"genre_scores_gemma":[0.9368411,0.002198104,0.05643184,0.0001640054,0.00002759284,0.0002723632,0.002070584,0.00004711989,0.001947399],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001211528,"threshold_uncertainty_score":0.002283573,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02722348509969026,"score_gpt":0.2119445729112299,"score_spread":0.1847210878115397,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}