{"id":"W1985570571","doi":"10.1002/anie.200701367","title":"Catalytic Enantioselective Reduction of β,β‐Disubstituted Vinyl Phenyl Sulfones by Using Bisphosphine Monoxide Ligands","year":2007,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":168,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Hydrosilylation; Phosphine; Enantioselective synthesis; Chemistry; Monoxide; Ligand (biochemistry); Carbon monoxide; Enantiomer; Catalysis; Alkyl; Combinatorial chemistry; Organic chemistry; Receptor","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002628669,0.0001987982,0.0002196313,0.0002621466,0.00009104054,0.00002903413,0.000221313,0.0001739922,0.0004371861],"category_scores_gemma":[0.0002204501,0.0002093897,0.0001520431,0.0006102488,0.0001017805,0.0004240174,0.00004298011,0.0001673075,0.0000104185],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004135134,"about_ca_system_score_gemma":0.00006395565,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003018521,"about_ca_topic_score_gemma":0.00001502816,"domain_scores_codex":[0.998338,0.000003510986,0.0005207252,0.0003417657,0.0005678875,0.0002280677],"domain_scores_gemma":[0.9987464,0.00007029118,0.0004034864,0.000187763,0.0004954627,0.00009661342],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001036309,0.0002058251,0.0004593958,0.00003145334,0.0002174637,0.000004929502,0.0001915358,0.000045446,0.993491,0.0001365104,0.002394758,0.002718038],"study_design_scores_gemma":[0.0006731678,0.0000117887,0.0001305818,0.00005897535,0.0000916507,0.00004004901,0.0003832093,0.0005429121,0.9952912,0.0001769057,0.002389444,0.0002100699],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9636531,0.0003170191,0.01904175,0.0001754628,0.00079775,0.00008304719,0.0002614617,0.000115169,0.01555527],"genre_scores_gemma":[0.9954573,0.0001021354,0.0001781632,0.00003046763,0.0007907268,0.000009952131,0.002501116,0.00002573556,0.0009044126],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03180422,"threshold_uncertainty_score":0.8538665,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01175285966672213,"score_gpt":0.2603343496105501,"score_spread":0.2485814899438279,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}