{"id":"W1985970551","doi":"10.1139/v01-010","title":"One-electron reduction of the γ*-isomer of [S<sub>2</sub>W<sub>18</sub>O<sub>62</sub>]<sup>4</sup> leads to isolation of the α-isomer","year":2001,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Polyoxometalates: Synthesis and Applications","field":"Materials Science","cited_by":18,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Isomerization; Chemistry; Cyclic voltammetry; Redox; Crystallography; Electrochemistry; Metal; Analytical Chemistry (journal); Stereochemistry; Physical chemistry; Inorganic chemistry; Electrode; Catalysis; Organic chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008480773,0.0004367064,0.0002030603,0.0001043691,0.0001272325,0.0001930347,0.0003028518,0.000154592,0.003457735],"category_scores_gemma":[0.0001785208,0.0002094125,0.0001190374,0.0001325476,0.0002157922,0.0002942981,0.0001510729,0.0003400662,0.0006308465],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000165946,"about_ca_system_score_gemma":0.0001324033,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004314777,"about_ca_topic_score_gemma":0.0011024,"domain_scores_codex":[0.999944,0.000005997551,0.00000371198,0.00001327174,0.00001817982,0.00001482453],"domain_scores_gemma":[0.9999512,0.000009239004,0.00001239583,0.000007912251,0.0000109497,0.000008207785],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001489458,0.00001096977,0.0001920074,0.00005974411,0.00000753533,0.00006196788,0.00003600758,0.00004853453,0.9963495,0.0002215897,0.000172366,0.002690922],"study_design_scores_gemma":[0.000007385845,0.000106067,0.000725834,0.000004066558,0.000006956267,0.00008760829,0.00004538514,0.0001980082,0.9962462,0.0001148955,0.002454119,0.000003426982],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.980836,0.0005719624,0.006766867,0.0001227424,0.00006868423,0.00004793642,0.0001920607,0.00009180086,0.01130199],"genre_scores_gemma":[0.9909354,0.0005071065,0.002472469,0.0000884194,0.000008122201,0.00002294896,0.0004005575,0.00004766645,0.005517324],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003457735,"threshold_uncertainty_score":0.01156723,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01251315299905638,"score_gpt":0.2155698949390476,"score_spread":0.2030567419399912,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}