{"id":"W1986057421","doi":"10.1139/v10-034","title":"Homoselenocysteine — An oxygen or selenium acid in the gas phase?","year":2010,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Free Radicals and Antioxidants","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Deprotonation; Protonation; Conformational isomerism; Intramolecular force; Hydrogen bond; Crystallography; Group (periodic table); Gas phase; Stereochemistry; Computational chemistry; Molecule; Organic chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.000361613,0.000170821,0.0002448344,0.00004563062,0.0001051471,0.0001044012,0.0008735533,0.0002110451,0.004756875],"category_scores_gemma":[0.0002085494,0.000116803,0.0001010046,0.0001668031,0.00015791,0.0001533312,0.000008327645,0.001010008,0.000006916652],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006140545,"about_ca_system_score_gemma":0.001375064,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005963722,"about_ca_topic_score_gemma":0.01407281,"domain_scores_codex":[0.9987413,0.00001476642,0.0004326027,0.0001542848,0.0002347677,0.0004222722],"domain_scores_gemma":[0.9985529,0.00004059092,0.0002044048,0.0003749234,0.0001076723,0.000719469],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000367621,0.00008525367,0.0008261208,0.00007700241,0.00002065362,0.0008463764,0.0003172461,0.000001306879,0.9912163,0.00001337677,0.002996567,0.003563031],"study_design_scores_gemma":[0.002204695,0.00006486096,0.0003135955,0.0001387045,0.00002996352,0.004046014,0.0009934434,0.00006209841,0.8877368,0.0001671908,0.1039574,0.0002852615],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9886732,0.0003558512,0.000003356432,0.0009535375,0.0001254053,0.00002194393,0.0000501999,0.000006534597,0.009809988],"genre_scores_gemma":[0.9978902,0.00002134754,0.0001463868,0.0001888767,0.001086229,0.000002190206,0.00001178558,0.00002288318,0.0006301457],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1034795,"threshold_uncertainty_score":0.9961529,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01274579857249535,"score_gpt":0.2421018931640801,"score_spread":0.2293560945915847,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}