{"id":"W1986064864","doi":"10.1002/rcm.1858","title":"Another designer steroid: discovery, synthesis, and detection of ‘madol’ in urine","year":2005,"lang":"en","type":"article","venue":"Rapid Communications in Mass Spectrometry","topic":"Hormonal and reproductive studies","field":"Medicine","cited_by":144,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"World Anti-Doping Agency","keywords":"Chemistry; Metabolite; Urine; Chromatography; Steroid; Context (archaeology); Mass spectrometry; Anabolism; Gas chromatography–mass spectrometry; Biochemistry; Hormone","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003826362,0.0001047796,0.0002929867,0.000466958,0.00004885431,0.00000789015,0.0001615209,0.00004721793,0.00002431344],"category_scores_gemma":[0.0001655931,0.0000871922,0.00003993237,0.0005858818,0.0002180127,0.0001233702,0.0001216184,0.0002306785,0.000003940136],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001234363,"about_ca_system_score_gemma":0.00001900366,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000766951,"about_ca_topic_score_gemma":0.0002816871,"domain_scores_codex":[0.9991299,0.0001249091,0.0002921619,0.0001900499,0.0001196575,0.0001433131],"domain_scores_gemma":[0.9988697,0.0002041143,0.00007336412,0.0007963326,0.0000356693,0.0000207914],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"observational","study_design_scores_codex":[0.0002738891,0.001206937,0.1760145,0.0001110631,0.0001591162,0.000003097103,0.0008941815,0.00001383171,0.7379259,0.001218892,0.0000324862,0.08214609],"study_design_scores_gemma":[0.0008386304,0.0001936985,0.8583366,0.0001345765,0.00004483442,0.00001961511,0.000940475,0.0002504715,0.1367974,0.0005117875,0.001783439,0.0001484051],"study_design_candidate":"observational","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.971076,0.01671848,0.001137216,0.004620865,0.00002107889,0.000328308,0.000004795497,0.00002314,0.006070092],"genre_scores_gemma":[0.9825548,0.00686899,0.01021278,0.00003301372,0.00004759183,0.00004565582,0.000002012649,0.00001328759,0.0002219014],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.6823221,"threshold_uncertainty_score":0.3555595,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02645155404136056,"score_gpt":0.2851228042613556,"score_spread":0.258671250219995,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}