{"id":"W1986074515","doi":"10.1139/v10-093","title":"Luminescence studies of copper(I)-containing [2]pseudorotaxanes","year":2011,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Supramolecular Chemistry and Complexes","field":"Chemistry","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Division of Chemistry; Conseil Régional d'Alsace","keywords":"Chemistry; Luminescence; Dichloromethane; Excited state; Ligand (biochemistry); Photochemistry; Copper; Steric effects; Crystallography; Stereochemistry; Organic chemistry; Solvent","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001637367,0.0002013258,0.0004133267,0.00004025234,0.0000841075,0.00001574667,0.0005531375,0.0001359308,0.001923755],"category_scores_gemma":[0.0004731898,0.0001988662,0.0001957612,0.0001160871,0.0003714257,0.0001029518,0.00002682638,0.0002975637,0.000002562125],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001034582,"about_ca_system_score_gemma":0.0008699584,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000417136,"about_ca_topic_score_gemma":0.0001477777,"domain_scores_codex":[0.9987279,0.000009166948,0.0005766376,0.0001610624,0.0001939981,0.0003312111],"domain_scores_gemma":[0.9982485,0.0000600588,0.0004958331,0.0003064174,0.0004151148,0.0004741398],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000599583,0.000027555,0.0163372,0.0005567152,0.0002650261,0.0006284892,0.002231992,0.000003152189,0.9782225,0.000024822,0.00094183,0.0007007737],"study_design_scores_gemma":[0.0003582571,0.00002320846,0.0001106594,0.0004151971,0.00005457902,0.0008322285,0.005831547,0.000002503034,0.9901914,0.0002737329,0.001709559,0.0001971141],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9534982,0.003979916,0.000008065587,0.00003885241,0.00009032976,0.00001367163,0.00001569753,0.000008599002,0.0423467],"genre_scores_gemma":[0.9986793,0.00004532997,0.0004203444,0.00003565781,0.0002085018,0.000002204102,0.00000348183,0.00002035729,0.0005848515],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04518111,"threshold_uncertainty_score":0.9989886,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0503334294162866,"score_gpt":0.2434721749545593,"score_spread":0.1931387455382726,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}