{"id":"W1986319865","doi":"10.1271/bbb.67.329","title":"Determination of the Absolute Configuration of (+)-Xestoaminol C [(2<i>S</i>, 3<i>R</i>)-2-Amino-3-tetradecanol], a Metabolite of Fiji Sponge,<i>Xestospongia</i>sp., by the Synthesis of Its…","year":2003,"lang":"en","type":"article","venue":"Bioscience Biotechnology and Biochemistry","topic":"Marine Sponges and Natural Products","field":"Biochemistry, Genetics and Molecular Biology","cited_by":26,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"University of Tokyo; Dalhousie University","keywords":"Sponge; Metabolite; Absolute configuration; Stereochemistry; Absolute (philosophy); Chemistry; Biology; Paleontology; Biochemistry; Philosophy","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004757121,0.0001808113,0.0002711735,0.00005826297,0.00008112421,0.000004653045,0.0005447133,0.0004252211,0.000007795422],"category_scores_gemma":[0.001041639,0.0001163674,0.0001083726,0.0004461499,0.001753111,0.000009746129,0.0001440739,0.0001419548,1.538031e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000007155076,"about_ca_system_score_gemma":0.0001175913,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001738829,"about_ca_topic_score_gemma":0.000003393848,"domain_scores_codex":[0.9986656,0.00007224656,0.0004676532,0.0003785474,0.0002115403,0.0002044133],"domain_scores_gemma":[0.9985397,0.00005263359,0.000592934,0.000604681,0.0001781821,0.00003189302],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002756806,0.00006839335,0.0006936188,0.0001462735,0.00001876425,1.701466e-7,0.00001266328,2.700053e-7,0.9908983,0.0005447265,0.0000715305,0.007517742],"study_design_scores_gemma":[0.0001789147,0.0001229029,0.002522178,0.00004047181,0.00005362514,0.00003078588,0.0000838753,0.00001886216,0.9945811,0.00003936559,0.002204777,0.0001231344],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9931858,0.005468033,0.00007864719,0.0005751847,0.0001124774,0.0002192566,0.0001263143,0.000006560649,0.0002276861],"genre_scores_gemma":[0.9979787,0.00125861,0.0003950674,0.00003153976,0.00001562157,0.000008324867,0.000009902924,0.000007491401,0.000294699],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007394607,"threshold_uncertainty_score":0.6459411,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006098176853932715,"score_gpt":0.2132662177882489,"score_spread":0.2071680409343161,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}