{"id":"W1986383306","doi":"10.1016/j.molstruc.2013.01.008","title":"Theoretical and experimental studies on the structure and spectroscopic properties of Ni(II) complexes of the type [Ni(L)(PPh3)] [H2L=5-methyl-N-(2-mercaptophenyl)salicylideneimine and 5-chloro-N-(2-mercaptophenyl)salicylideneimine]","year":2013,"lang":"en","type":"article","venue":"Journal of Molecular Structure","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":8,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Windsor","funders":"","keywords":"Chemistry; Crystallography; Stereochemistry; Computational chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003279567,0.0004246383,0.001064115,0.0001383828,0.0002212578,0.00005961851,0.0003014136,0.000152966,0.0003007435],"category_scores_gemma":[0.0006828925,0.0001924544,0.0001579841,0.0001904074,0.001658186,0.0001239631,0.0003343452,0.0005318596,3.785676e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003450783,"about_ca_system_score_gemma":0.00008070232,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004483111,"about_ca_topic_score_gemma":0.000005309357,"domain_scores_codex":[0.9975218,0.0003522143,0.0008551472,0.0003019002,0.0006912323,0.0002776706],"domain_scores_gemma":[0.9981554,0.0001565408,0.0006202431,0.0004696896,0.0004526665,0.0001454844],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004385317,0.00004857827,0.001335083,0.000269239,0.0005280426,0.000007787725,0.002403268,0.000009381304,0.9821088,0.01240226,0.0001644828,0.0002845009],"study_design_scores_gemma":[0.0008807342,0.001498805,0.01328975,0.0006427992,0.0003202838,0.000481005,0.00271589,0.00004835258,0.9714389,0.008414307,0.00006943908,0.0001997063],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9649237,0.03084263,0.000002290611,0.003271924,0.0002805909,0.0005569069,0.00001480184,0.000006989732,0.0001001558],"genre_scores_gemma":[0.9977025,0.0004451779,0.000871198,0.0007217274,0.0001526148,0.000004001854,0.000001104885,0.00004244549,0.00005916129],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03277886,"threshold_uncertainty_score":0.7848065,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02603140231005966,"score_gpt":0.2730891005691047,"score_spread":0.247057698259045,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}