{"id":"W1986485569","doi":"10.1002/adsc.201400463","title":"Copper Catalysts for Selective CC Bond Cleavage of β‐O‐4 Lignin Model Compounds","year":2014,"lang":"en","type":"article","venue":"Advanced Synthesis & Catalysis","topic":"Lignin and Wood Chemistry","field":"Engineering","cited_by":88,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; Los Alamos National Laboratory; Ontario Ministry of Economic Development and Innovation; University of Ottawa","keywords":"Chemistry; Catalysis; Bond cleavage; Selectivity; Aldehyde; Lignin; Aryl; Copper; Organic chemistry; Alcohol oxidation; Ether; Alcohol; Medicinal chemistry; Alkyl","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.00018548,0.0002991198,0.0006023705,0.0001155047,0.00008556421,0.00001781595,0.0003134536,0.0001421776,2.511787e-7],"category_scores_gemma":[0.0001574556,0.0003101779,0.0002708089,0.0002964672,0.00007377451,0.0001949501,0.00003909078,0.0001192765,0.00001616299],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009932406,"about_ca_system_score_gemma":0.00002344415,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001032644,"about_ca_topic_score_gemma":0.00001639257,"domain_scores_codex":[0.9986001,0.00001416534,0.0004119514,0.0003726346,0.0002126574,0.0003884524],"domain_scores_gemma":[0.9986037,0.0004744933,0.0001048709,0.000589986,0.0001068822,0.0001200554],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002801237,0.0002317283,0.00009493875,0.0003938714,0.0005064037,8.446656e-7,0.000423833,0.002948601,0.7931179,0.0001776642,0.1968132,0.005263006],"study_design_scores_gemma":[0.0006147037,0.00002030345,0.000009436382,0.00005392628,0.0002610052,0.000002231387,0.0001060443,0.01069895,0.9868093,0.0004519737,0.0006227697,0.0003493781],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.3121401,0.002805901,0.01585984,0.0003713657,0.0006894636,0.001867664,0.001217039,0.002403928,0.6626447],"genre_scores_gemma":[0.989175,0.00004208278,0.01013941,0.00002926341,0.00006479122,0.0001971468,0.00009454636,0.00008447805,0.000173301],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.6770349,"threshold_uncertainty_score":0.999935,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005918887911476487,"score_gpt":0.2088680717317686,"score_spread":0.2029491838202921,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}