{"id":"W1986494820","doi":"10.1021/ic802320s","title":"Synthesis of N,C Bound Sulfur, Selenium, and Tellurium Heterocycles via the Reaction of Chalcogen Halides with −CH<sub>3</sub> Substituted Diazabutadiene Ligands","year":2009,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":34,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Chemistry; Chalcogen; Tellurium; Selenium; Halide; Sulfur; Medicinal chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.000135168,0.0003520321,0.0004602369,0.00004103955,0.0001332213,0.00003475281,0.0002926099,0.0002842327,0.00006304069],"category_scores_gemma":[0.000110525,0.000281701,0.0001070774,0.0002512837,0.0002424589,0.0001456748,0.00005985675,0.0003061543,0.000004047097],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000130767,"about_ca_system_score_gemma":0.0000930837,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005749972,"about_ca_topic_score_gemma":0.00001983345,"domain_scores_codex":[0.9982832,0.00001292651,0.0005133831,0.0004648893,0.0003932336,0.0003323688],"domain_scores_gemma":[0.9983436,0.0001692564,0.0004908362,0.0006743409,0.0001946364,0.0001273227],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001446282,0.0001396056,0.0003100272,0.000459013,0.0001103589,0.000009170849,0.0003094056,0.000004084707,0.9920328,0.000007435105,0.000007098727,0.00646639],"study_design_scores_gemma":[0.0004959878,0.00003126447,0.0008688613,0.0001931326,0.0002128448,0.0004210313,0.0005480151,0.00001987678,0.9967275,0.0001133617,0.00006904815,0.0002990576],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9979199,0.0005410038,0.00005202993,0.0001095561,0.00003150732,0.0001031251,0.00003435155,0.0001075631,0.001100937],"genre_scores_gemma":[0.999268,0.0003641806,0.00005976461,0.00001285881,0.0001580769,0.00001623303,0.00003405951,0.00004607773,0.00004074192],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006167332,"threshold_uncertainty_score":0.9999635,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005974012854364902,"score_gpt":0.1893522202443624,"score_spread":0.1833782073899975,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}