{"id":"W1986586041","doi":"10.1021/ja049915u","title":"<i>trans-</i>Bis(alkynyl) Diruthenium(III) Tetra(amidinate):  An Effective Facilitator of Electronic Delocalization","year":2004,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":111,"is_retracted":false,"has_abstract":true,"ca_institutions":"Carleton University","funders":"","keywords":"Chemistry; Facilitator; Tetra; Delocalized electron; Medicinal chemistry; Computational chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003107059,0.0002226128,0.000499289,0.00002364642,0.0001216472,0.00003096613,0.0005556067,0.0001161816,0.00003534834],"category_scores_gemma":[0.000202041,0.0001674815,0.0008295132,0.0005221245,0.0006958022,0.0001751267,0.00006007193,0.0007873348,0.000001071642],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001009653,"about_ca_system_score_gemma":0.000299489,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002417884,"about_ca_topic_score_gemma":0.000006766834,"domain_scores_codex":[0.9982609,0.000005879791,0.0005915514,0.0002302015,0.0005288801,0.0003826032],"domain_scores_gemma":[0.9980692,0.0002180159,0.0008755665,0.0003959134,0.0002902323,0.0001510427],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000143709,0.0003054326,0.0007574062,0.0000492069,0.0002260865,0.000001014984,0.001096804,0.001452489,0.9946058,0.00004540251,0.0001363851,0.001180264],"study_design_scores_gemma":[0.001248816,0.0001161755,0.0004972559,0.00008264057,0.000194018,0.00009803999,0.001220347,0.0003875647,0.9942531,0.0007604003,0.0009465414,0.000195107],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9962088,0.0001625931,0.002977543,0.0003764029,0.00007199262,0.00008912358,0.00003299137,0.00003319956,0.00004728235],"genre_scores_gemma":[0.9993585,0.00007860547,0.0001839476,0.0001218979,0.000174973,0.000006187265,0.000007802531,0.00003365331,0.00003446767],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003149594,"threshold_uncertainty_score":0.6829696,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00474906072572413,"score_gpt":0.2510443651118791,"score_spread":0.246295304386155,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}