{"id":"W1986619497","doi":"10.1016/j.crci.2003.10.001","title":"Monomer compartmentalisation in miniemulsion polymerisation studied by infrared spectroscopy","year":2003,"lang":"en","type":"article","venue":"Comptes Rendus Chimie","topic":"Advanced Polymer Synthesis and Characterization","field":"Chemistry","cited_by":13,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Miniemulsion; Attenuated total reflection; Polymer chemistry; Styrene; Monomer; Copolymer; Fourier transform infrared spectroscopy; Polymerization; Infrared spectroscopy; Chemistry; Materials science; Physics; Polymer; Optics; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00006065947,0.0002197892,0.0002618039,0.00007510454,0.0001084176,0.00003638261,0.0001133994,0.0001046734,0.002726704],"category_scores_gemma":[0.00002665817,0.0002308366,0.00005104234,0.0001576001,0.00004579446,0.0001917436,0.00002370585,0.000148948,0.00005655194],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001445193,"about_ca_system_score_gemma":0.00001787742,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001350072,"about_ca_topic_score_gemma":0.000004585972,"domain_scores_codex":[0.9987584,0.00005080495,0.0003939871,0.0003306275,0.0001962804,0.0002699074],"domain_scores_gemma":[0.9993833,0.00006319224,0.0001972938,0.0002695249,0.00001638086,0.00007031355],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005567184,0.0003038916,0.03389378,0.00002303296,0.00002688436,0.000001688857,0.000400711,0.00001977696,0.9588542,0.0001913089,0.004042441,0.002186604],"study_design_scores_gemma":[0.0009039293,0.00002522959,0.00455299,0.00004685797,0.00001513381,0.000002284189,0.0003670053,0.0003742728,0.9805632,0.0002086983,0.01265522,0.0002852407],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9745844,0.002034066,0.0005525158,0.00007363808,0.0001753108,0.000108427,0.00005008719,0.00008440297,0.02233717],"genre_scores_gemma":[0.9975693,0.0002091616,0.0005436209,0.0001011053,0.00005834482,0.00004729222,0.0004784768,0.00003028011,0.0009624535],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02934078,"threshold_uncertainty_score":0.9981849,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0135906924343854,"score_gpt":0.2424655079152441,"score_spread":0.2288748154808587,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}