{"id":"W1986696832","doi":"10.1002/chin.200016076","title":"ChemInform Abstract: Use of γ‐Carboxy‐α,β‐unsaturated Aldehydes as Synthetic Equivalents of β,γ‐Unsaturated Aldehydes in a Novel Stereoselective Approach to Diketides.","year":2000,"lang":"en","type":"article","venue":"ChemInform","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Stereoselectivity; Combinatorial chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003582991,0.0009653764,0.0002202191,0.0005440483,0.0002579789,0.0004664173,0.0006321122,0.0003829327,0.006107899],"category_scores_gemma":[0.0001982161,0.0002829822,0.0002974427,0.0003799023,0.000305614,0.0008412857,0.0005915361,0.0009275997,0.003518598],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004232863,"about_ca_system_score_gemma":0.0006732345,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005493033,"about_ca_topic_score_gemma":0.000737183,"domain_scores_codex":[0.9997545,0.00003075848,0.00002529984,0.00005864576,0.00005764219,0.00007313884],"domain_scores_gemma":[0.9999086,0.000008814231,0.00001798585,0.00001062344,0.00001672363,0.00003735024],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0008629917,0.0002171185,0.0002355203,0.0005262659,0.00004487741,0.0008378929,0.0001526843,0.0008976501,0.9424854,0.008213755,0.005532103,0.03999379],"study_design_scores_gemma":[0.00006137376,0.0005723436,0.0003165148,0.00002026275,0.0000263649,0.0004949601,0.00002528256,0.0004293001,0.9782616,0.0004086302,0.01936264,0.00002079635],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.5951682,0.01406957,0.1219139,0.001774029,0.003472803,0.001038233,0.005713616,0.002904253,0.2539455],"genre_scores_gemma":[0.9223453,0.009762405,0.02277706,0.0004291447,0.0001803816,0.0001480621,0.00210492,0.0002491353,0.04200362],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006107899,"threshold_uncertainty_score":0.02043295,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0269400375161589,"score_gpt":0.2402663425495172,"score_spread":0.2133263050333583,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}