{"id":"W1986951230","doi":"10.1016/s0378-3812(02)00325-4","title":"Excess enthalpies of the ternary mixtures: diisopropyl ether + (2,2,4-trimethylpentane or n-heptane) + methylcyclohexane at 298.15 K","year":2003,"lang":"en","type":"article","venue":"Fluid Phase Equilibria","topic":"Thermodynamic properties of mixtures","field":"Chemical Engineering","cited_by":4,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Ottawa","funders":"","keywords":"Diisopropyl ether; Methylcyclohexane; Chemistry; Ternary operation; Enthalpy; Heptane; UNIFAC; Ether; Physical chemistry; Thermodynamics; Organic chemistry; Activity coefficient; Toluene","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0004682188,0.0005757422,0.0006985381,0.0001095341,0.0001413905,0.00003956636,0.001261067,0.0003169547,0.00471538],"category_scores_gemma":[0.0008258816,0.0003587115,0.0003867583,0.0004238249,0.0003457513,0.0002475519,0.0005158297,0.0004798158,0.00008437544],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002266079,"about_ca_system_score_gemma":0.0001118873,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001153244,"about_ca_topic_score_gemma":0.00001981362,"domain_scores_codex":[0.9967783,0.0003182131,0.0007988233,0.0006343278,0.0007277546,0.0007425633],"domain_scores_gemma":[0.9975723,0.0004330495,0.0002649868,0.001416742,0.00009784727,0.0002150792],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0007455567,0.0003186218,0.0001307072,0.0001594005,0.0002698513,0.00004848015,0.00087554,0.00008053627,0.9922429,0.0006787233,0.003165594,0.001284063],"study_design_scores_gemma":[0.003083413,0.0001852328,0.00005084654,0.0001822559,0.0001437512,0.0001430553,0.0001165907,0.004865958,0.9667887,0.0007008305,0.02316251,0.0005768416],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9829252,0.008078416,0.001052512,0.0002226653,0.001140762,0.000606243,0.0001279394,0.000251385,0.005594872],"genre_scores_gemma":[0.9778207,0.00006633006,0.001204858,0.0002074248,0.0002616031,0.00005396638,0.00002983828,0.0001675936,0.02018767],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02545421,"threshold_uncertainty_score":0.9998865,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01999727971450287,"score_gpt":0.2714576625677962,"score_spread":0.2514603828532934,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}