{"id":"W1986962638","doi":"10.1021/ol048892l","title":"One-Pot, Three-Component Synthesis of Linearly Substituted Homoallylic Alcohols via Allyl(isopropoxy)dimethylsilane","year":2004,"lang":"en","type":"article","venue":"Organic Letters","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":14,"is_retracted":false,"has_abstract":true,"ca_institutions":"Merck Canada Inc. (Canada)","funders":"","keywords":"Dimethylsilane; Chemistry; Component (thermodynamics); Medicinal chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000120423,0.0003535727,0.000217339,0.0002156075,0.0001684289,0.0002328417,0.0003336663,0.0001632954,0.001153048],"category_scores_gemma":[0.00008904356,0.0001412382,0.0001540907,0.0001824506,0.0001543074,0.0002674583,0.0002621156,0.0003459738,0.0005866904],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002933569,"about_ca_system_score_gemma":0.0002903277,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003009593,"about_ca_topic_score_gemma":0.001250165,"domain_scores_codex":[0.999913,0.00000785583,0.000006661588,0.00002219399,0.00002313766,0.00002712163],"domain_scores_gemma":[0.9999437,0.000006641013,0.00001352871,0.000009261076,0.000009462206,0.00001750143],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005060176,0.00005530973,0.0001355176,0.0000943976,0.000008767224,0.000123747,0.00004921728,0.0003806646,0.9847745,0.001301403,0.000211397,0.01281444],"study_design_scores_gemma":[0.000006689179,0.0001064751,0.0003258209,0.000001933091,0.000006897786,0.00007095577,0.000008046974,0.000458138,0.9962655,0.00006864656,0.002677426,0.000003612756],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8995581,0.001760203,0.07301466,0.0002393773,0.0001312733,0.0002360505,0.0008312013,0.001008136,0.02322102],"genre_scores_gemma":[0.9647455,0.0009419532,0.02838862,0.000049418,0.00001394489,0.00004727024,0.000299309,0.00005202103,0.005461955],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001153048,"threshold_uncertainty_score":0.003857315,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01647365498610261,"score_gpt":0.235621716085298,"score_spread":0.2191480610991954,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}